Multifilament nickel-titanium alloy drawn superelastic wire

Electricity: conductors and insulators – Conduits – cables or conductors – Conductor structure

Reexamination Certificate

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Reexamination Certificate

active

06215073

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to wires having a low modulus of elasticity. More particularly, the present invention is related to improvements in nickel-titanium alloy wires. The present invention has application to many arts, including the guidewire arts of some of the parent applications hereof, the electrical cable arts of others of the parent applications hereof, etc.
2. State of the Art
Wire is manufactured from ingots using a rolling mill and a drawing bench. The preliminary treatment of the material to be manufactured into wire is done in the rolling mill where white hot billets (square section ingots) are rolled to round wire rod. The action of atmospheric oxygen causes a coating of mill scale to form on the hot surface of the rod and must be removed. This descaling can be done by various mechanical methods (e.g., shot-blasting) or by pickling, i.e., immersion of the wire rod in a bath of dilute sulphuric or hydrochloric acid or mixtures with hydrofluoric acid. After pickling, the wire rod may additionally undergo a jolting treatment which dislodges the scale loosened by the acid. The remaining acid is removed by immersion of the wire rod in lime water.
The actual process of forming the wire is called drawing and is carried out on the metal in a cold state with a drawing bench. Prior art
FIG. 1
shows a simple drawing bench
10
. The wire
12
is pulled through a draw plate
14
which is provided with a number of holes, e.g. 16, (dies) of various diameters. These dies have holes which taper from the diameter of the wire
12
that enters the die to the smaller diameter of the wire
12
′ that emerges from the die. The thick wire rod
12
is coiled on a vertical spool
18
called a swift and is pulled through the die by a rotating drum
20
mounted on a vertical shaft
22
which is driven by bevel gearing
24
. The drum can be disconnected from the drive by means of a clutch
26
. To pass a wire through a die, the end of the wire is sharpened to a point and threaded through the die. It is seized by a gripping device and rapidly pulled through the die. This is assisted by lubrication of the wire. Each passage through a die reduces the diameter of the wire by a certain amount. By successively passing the wire through dies of smaller and smaller diameter, thinner and thinner wire is obtained. The dies used in the modern wire industry are precision-made tools, usually made of tungsten carbide for larger sizes or diamond for smaller sizes. The die design and fabrication is relatively complex and dies may be made of a variety of materials including single crystal natural or synthetic diamond, polycrystalline diamond or a mix of tungsten and cobalt powder mixed together and cold pressed into the carbide nib shape.
A cross section of die
16
is shown in prior art FIG.
2
. Generally, the dies used for drawing wire have an outer steel casing
30
and an inner nib
32
which, as mentioned above, may be made of carbide or diamond or the like. The die has a large diameter entrance
34
, known as the bell, which is shaped so that wire entering the die will draw lubricant with it. The shape of the bell causes the hydrostatic pressure to increase and promotes the flow of lubricant into the die. The region
36
of the die where the actual reduction in diameter occurs is called the approach angle. In the design of dies, the approach angle is an important parameter. The region
38
following the approach angle is called the bearing region. The bearing region does not cause diametric reduction, but does produce a frictional drag on the wire. The chief function of the bearing region
38
is to permit the conical approach surface
36
to be refinished (to remove surface damage due to die wear) without changing the die exit. The last region
40
of the die is called the back relief. The back relief allows the metal wire to expand slightly as the wire leaves the die. It also minimizes the possibility of abrasion taking place if the drawing stops or if the die is out of alignment with the path of the wire.
Although wire drawing appears to be a simple metalworking process, those skilled in the art will appreciate that many different parameters affect the physical quality of the drawn wire. Among these parameters, draw stress and flow stress play an important role. If these parameters are not carefully considered, the drawn wire may have reduced tensile strength. A discussion of the practical aspects of wire drawing can be found in Wright, Roger N., “Mechanical Analysis and Die Design”, Wire Journal, October 1979, the complete disclosure of which is hereby incorporated by reference herein.
The wire forming processes described above may be used to form different kinds of wires. Generally, various characteristics of the formed wire are of interest, depending upon the art in which the wire is to be used. These aspects include, but are not limited to the electrical resistance, tensile strength, and flexibility of the wire. Wire flexibility is particularly important in the medical arts which utilize wires in inter alia stents and guidewires, although wire flexibility is important in other arts as well. For that reason, the medical arts have had much interest recently in nickel-titanium (Nitinol) alloy wires which exhibit superelastic characteristics.
SUMMARY OF THE INVENTION
It is therefore an object of the invention to provide nickel-titanium alloy cables which exhibit improved flexibility characteristics over the nickel-titanium alloy wires of the art.
In accord with this object which will be discussed in detail below, the highly flexible cable of the present invention includes two and preferably three or more strands of nickel-titanium alloy wire which are twined to form a wire rope. The nickel-titanium alloy wire rope is drawn through successive dies to reduce its diameter until the outer surface of the cable is substantially smooth, the cross section of the cable is substantially circular, and the overall diameter of the wire rope is reduced by 20-50%. The cable is then annealed to remove the effects of cold working, and the resulting cable/wire has been found to have an improved flexibility (i.e., a lower modulus of elasticity) relative to single strand nickel-titanium wires of the same diameter.
Additional objects and advantages of the invention will become apparent to those skilled in the art upon reference to the detailed description taken in conjunction with the provided figures.


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