Multi-step process to incorporate grain growth inhibitors in WC-

Metal treatment – Process of modifying or maintaining internal physical... – Carburizing or nitriding using externally supplied carbon or...

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148423, 148425, C23C 820

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active

058853723

ABSTRACT:
Grain growth inhibitors including vanadium carbide, chromium carbide, tantalum carbide, and niobium carbide are incorporated into a cobalt/tungsten carbide matrix during the formation of the cobalt/tungsten carbide matrix. A precursor powder is formed by combining in solution a cobalt composition, a tungsten composition and a grain growth inhibiting metal composition, which is then spray dried. The precursor compound is then carburized in carbon monoxide and carbon dioxide to form cobalt/tungsten carbide matrix. This is then further carburized in a hydrocarbon hydrogen gas at an elevated temperature to cause the grain growth inhibiting metal present to form the carbide. The second carburizing step is conducted with a carburizing gas having a carbon activity greater than about 2 for a relatively short period of time at 900.degree. C. to 1000.degree. C.

REFERENCES:
patent: 4234333 (1980-11-01), Ghandehari et al.
patent: 5230729 (1993-07-01), McCandlish et al.
patent: 5352269 (1994-10-01), Mcandlish et al.
Wu, L., Nanostructure Tungsten Carbide/Cobalt Alloys: Processing and Properties, Dissertation Abstracts International 54, (9) May 1993.

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