Multi-stage hydrodesulfurization of cracked naphtha streams...

Mineral oils: processes and products – Refining – Sulfur removal

Reexamination Certificate

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C208S209000, C208S213000, C208S21600R, C208S059000, C208S217000

Reexamination Certificate

active

06913688

ABSTRACT:
A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically bound sulfur and olefins. The olefinic naphtha stream is selectively hydrodesulfurized in a first sulfur removal stage and resulting product stream, which contains hydrogen sulfide and organosulfur is fractionated at a temperature to produce a light fraction containing less than about 100 wppm organically bound sulfur and a heavy fraction containing greater than about 100 wppm organically bound sulfur. The light fraction is stripped of at least a portion ofits hydrogen sulfide and can be collected or passed to gasoline blending. The heavy fraction is passed to a second sulfur removal stage wherein at least a portion of any remaining organically bound sulfur is removed.

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S. J. Tauster, et al., “Structure and Properties of Molybdenum Sulfide: Correction of O2Chemisorption with Hydrodesulfurization Activity,” Journal of Catalysis 63, pp. 515-519 (1980).

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