Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2007-10-30
2007-10-30
Pezzuto, Helen L (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S287000, C526S288000, C526S307500, C526S307600, C526S307700, C526S318400, C526S318500, C526S320000, C526S328500, C526S329600
Reexamination Certificate
active
10338275
ABSTRACT:
Disclosed are multi-purpose alkali-swellable and alkali soluble associative polymers, which are the polymerization product of a monomer mixture comprising: (a) at least one acidic vinyl monomer; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) a monomer selected from the group consisting of a second associative monomer having a second hydrophobic end, a semihydrophobic monomer and a combination thereof; and, optionally, (e) one or more crosslinking monomers or chain transfer agents. When monomer (d) is an associative monomer, the first and second hydrophobic end groups of monomers (c) and (d) have significantly different hydrophobic and/or steric character from one another. The multi-purpose associative polymers surprisingly provide desirable Theological and aesthetic properties in aqueous media.
REFERENCES:
patent: 4384096 (1983-05-01), Sonnabend
patent: 4421902 (1983-12-01), Chang et al.
patent: 4426485 (1984-01-01), Hoy et al.
patent: 4514552 (1985-04-01), Shay et al.
patent: 4600761 (1986-07-01), Ruffner et al.
patent: 4616074 (1986-10-01), Ruffner
patent: 4743698 (1988-05-01), Ruffner et al.
patent: RE33156 (1990-01-01), Shay et al.
patent: 4892916 (1990-01-01), Hawe et al.
patent: 4904772 (1990-02-01), Sau
patent: 5011978 (1991-04-01), Barron et al.
patent: 5102936 (1992-04-01), Huth et al.
patent: 5137571 (1992-08-01), Eisenhart et al.
patent: 5191051 (1993-03-01), Shay et al.
patent: 5292828 (1994-03-01), Jenkins et al.
patent: 5292843 (1994-03-01), Jenkins et al.
patent: 5294692 (1994-03-01), Barron et al.
patent: 5342883 (1994-08-01), Jenkins et al.
patent: 5352734 (1994-10-01), Jenkins et al.
patent: 5362415 (1994-11-01), Egraz et al.
patent: 5399618 (1995-03-01), Jenkins et al.
patent: 5401802 (1995-03-01), Jenkins et al.
patent: 5405900 (1995-04-01), Jenkins et al.
patent: 5412142 (1995-05-01), Wilkerson, III et al.
patent: 5426182 (1995-06-01), Jenkins et al.
patent: 5436292 (1995-07-01), Jenkins et al.
patent: 5461100 (1995-10-01), Jenkins et al.
patent: 5476900 (1995-12-01), Jenkins et al.
patent: 5478602 (1995-12-01), Shay et al.
patent: 5486587 (1996-01-01), Shay et al.
patent: 5488180 (1996-01-01), Jenkins et al.
patent: 5561189 (1996-10-01), Jenkins et al.
patent: 5629375 (1997-05-01), Jenkins et al.
patent: 5639841 (1997-06-01), Jenkins
patent: 5681882 (1997-10-01), Jenkins et al.
patent: 5708068 (1998-01-01), Carder et al.
patent: 5739196 (1998-04-01), Jenkins et al.
patent: 5739378 (1998-04-01), Jenkins et al.
patent: 5770760 (1998-06-01), Robinson
patent: 5863973 (1999-01-01), Carder et al.
patent: 5916967 (1999-06-01), Jones et al.
patent: 6063857 (2000-05-01), Greenblatt et al.
patent: 6083422 (2000-07-01), Ambuter et al.
patent: 6106578 (2000-08-01), Jones
patent: 6140435 (2000-10-01), Zanotti-Russo
patent: 6329447 (2001-12-01), Avramidis et al.
patent: 6337366 (2002-01-01), Amick et al.
patent: 6451299 (2002-09-01), Rigoletto, Jr. et al.
patent: 2002/0002934 (2002-01-01), Nungesser et al.
patent: 2002/0042448 (2002-04-01), Sorrentino et al.
patent: 0 398 576 (1990-11-01), None
patent: 0 444 791 (1991-09-01), None
patent: 1 038 892 (2000-09-01), None
patent: 2777011 (1999-10-01), None
patent: WO96/35757 (1996-11-01), None
Kennedy et al. J. Chem. Soc. Faraday Trans., 1995, 91(5), 911-916.
Riggoletto, R., Jr., et al., “Styleze™2000—A New Fixative Polymer for Gels-Formulation and Processing Guide (Part I),”Soap&Cosmetics, pp. 43-46 (Jul./Aug. 2001).
Riggoletto, R., Jr., et al., “Styleze™2000—A New Fixative Polymer for Gels-Formulation and Processing Guide (Part II),”Soap&Cosmetics, pp. 39-43 (Sep. 2001).
Shay, G.D., “Alkali-Swellable and Alkali-Soluble Thickener Technology—A Review,”Polymers in Aqueous Media, Performance Through Association, Advances in Chemistry Series, 223, Ch. 25, pp. 457-494, The American Chemical Society, (1989).
Diaz, P., et al., “Set Relaxation of Human Hair,”J. Soc. Cosmet. Chem., 34, pp. 205-212 (Jul. 1983).
Rieger, M.J., Ph.D. (ed.),Harry's Cosmeticology, 8thEd., Ch. 30, pp. 666-667, Chemical Publishing Co., Inc., New York, NY (2000).
R.K. Gupta et al., “Rheological Properties of Model Alkali-Soluble Associative (HASE) Polymers: Effect of Varying Acid Monomer and Macromonomer Composition”, Proceedings of the International Congress on Rheology, 13th, Cambridge, United Kingdom, Aug. 20-25, 2000, vol. 1, 340-342.
R.K. Gupta et al., “Interactions of Methylated.Beta.-Cyclodextrin With Hydrophobically Modified Alkali-Soluble Associative Polymers (HASE): Effect of Varying Carbon Chain Length”, Proceedings of the International Congress on Rheology, 13th, Cambridge, United Kingdom, Aug. 20-25, 2000, vol. 1, 335-337.
Dr. F. L'Alloret et al., “Aqueous Solution Behavior of New Thermoassociative Polymers”, Colloid Polymer Science, vol. 273, No. 12, Dec. 1995, pp. 1163-1173.
D. Hourdet et al., “Synthesis of Thermoassociative Copolymers”, Polymer, vol. 38, No. 10, May 1, 1997, pp. 2535-2547.
W.K. NG et al., Rheological Properties of Methacrylic Acid/Ethyl Acrylate Co-polymer: Comparison Between an Unmodified and Hydrophobically Modified System, Polymer, 42, pp. 249-259, 2002.
Sheng Dai et al., Dynamic Light Scattering of Semidilute Hydrophobically Modified Alkali-Soluble Emulsion Solutions with Different Lengths of Poly(ethylene oxide) Spacer Chain, J. Polymer Science: Part B: Polymer Physics, vol. 43, pp. 3288-3298, 2005.
Ahmed A. Abdala et al., Solution Rheology of Hydrophobically Modified Associate Polymers: Effects of Backbone Composition and Hydrophobe Concentration, J. Soc. Rheol., 48(5), pp. 979-994, Sep./Oct. 2004.
Robert J. English et al., Associative Polymers Bearing n-alkyl Hydrophobes: Rheological Evidence for Microgel-like Behavior, J. Soc. Rheol., 43(5), pp. 1175-1194, Sep./Oct. 1999.
K. C. Tam et al., Rheological Properties of Hydrophobically Modified Alkali-Soluble Polymers-Effects of Ethlene-Oxide Chain Length, J. Polymer Science: Part B: Polymer Physics, vol. 36, pp. 2275-2290, 1998.
CRC Handbook of Solubility Parameters and Other Cohesion Parameters, CRC Press, Inc., 1983, p. 76.
Barker Thomas A.
Ramey Kittie L.
Shah Pravinchandra K.
Tamareselvy Krishnan
Dunlap Thoburn T.
Lubrizol Advanced Materials, Inc.
Olson & Hierl Ltd.
Pezzuto Helen L
LandOfFree
Multi-purpose polymers, methods and compositions does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Multi-purpose polymers, methods and compositions, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Multi-purpose polymers, methods and compositions will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3844596