Cleaning compositions for solid surfaces – auxiliary compositions – Auxiliary compositions for cleaning – or processes of preparing – Textile softening or antistatic composition
Reexamination Certificate
2000-06-29
2002-03-26
Hardee, John (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Auxiliary compositions for cleaning, or processes of preparing
Textile softening or antistatic composition
C510S525000, C510S527000
Reexamination Certificate
active
06362158
ABSTRACT:
This invention relates to rinse cycle fabric softener compositions. More particularly, it relates to an aqueous multi-phase liquid fabric softener composition comprising at least two transparent or translucent phases.
Multi-phase compositions which are transparent or clear are well-known in products intended for personal care such as bath oils and shower products, but not in fabric softening compositions. The various technologies which are used to obtain a clear multi-phase aesthetic effect generally rely on compositions containing oil and/or anionic surfactants that are generally incompatible with cationic surfactants and, particularly with the type of cationic surfactant required to provide a fabric softening composition which is both efficacious and transparent or clear.
Clear single phase fabric softening compositions are described in the patent literature. U.S. Pat. Nos. 5,525,245 and 5,656,585 assigned to Colgate-Palmolive, and U.S. Pat. No. 5,427,697 to Procter & Gamble describe single phase solutions or microemulsions which contain fabric softening ingredients. The microemulsions of the aforementioned '245 and '585 patents are said to be converted to macroemulsions having a turbid or milky appearance upon dilution with water in the rinse cycle thereby enabling fabric softening to occur.
While consumer preference often favors the aesthetic of clarity in fabric softener compositions, there remains as an object of the prior art the ability to provide a multi-phase fabric softener composition in which all phases are either clear or transparent or translucent, notwithstanding that such composition contains one or more cationic softening ingredients. In addition to the enhanced aesthetic properties, the resulting composition must also provide efficacious fabric softening when used as a rinse cycle softening composition.
SUMMARY OF THE INVENTION
The objects cited above are satisfied by an aqueous multi-phase liquid fabric softener composition comprised of at least two phases, all of said phases being transparent or translucent, said fabric softener composition comprising:
(a) from about 5% to about 45%, by weight, of a cationic softening material;
(b) from about 5% to about 15%, by weight, of a solvent having a partition coefficient of log P of from about 0.70 to about 2.0;
(c) from about 0.2% to about 1.5%, by weight, of a mineral electrolyte;
(d) a water-immiscible oil-based perfume in a sufficient amount to provide the desired degree of fragrance; and
(e) balance water whereby said multi-phase softener composition is capable of being converted to a milky macroemulsion upon dilution with water.
The present invention is predicated upon the discovery that the selection of a solvent and a mineral electrolyte in accordance with the invention when combined with a diester quaternary ammonium fabric softener as herein described provide an efficacious liquid fabric softener having at least two phases and wherein each phase manifests the desired aesthetic property of being transparent or translucent.
All of the ingredients of the softening composition must be normally liquid, namely, liquid at ambient room-temperature.
DETAILED DESCRIPTION OF THE INVENTION
The cationic softening material for purposes of the invention is preferably a diester quaternary ammonium surfactant fabric softener selected from the group having the structural formulae as follows:
wherein each
A is independently C(O)O—R′ or —(O(O)—C—R′;
R is a lower group having 1 to about 4 carbon atoms;
R′ is an alkyl or alkenyl group having 8 to about 22 carbon atoms;
R″ is independently a lower alkyl radical having 1 to about 6 carbon atoms or hydroxyl alkyl group;
n is an integer having a value of 1 to about 3;
X is a softener compatible anion, preferably selected from the group consisting of a halide ion and methyl or ethyl sulfate; and
wherein B independently is A or (R)
n
—A; and A, R, R″ and n are as defined above; and
wherein A, R, R″ and n are as defined above.
The preferred diester quaternary ammonium surfactant fabric softeners are represented by equation (I) above and are commercially available from Stepan Co. as Stepantex and from Kao Corp. as Tetranyl but can also be synthesized by the reaction of two moles of a fatty acid with a trialkanolamine optionally followed by alkoxylation and methylation with dimethyl sulfate or an alkyl halide such as, methyl iodide. In a preferred mode the fatty acid is oleic acid and ethylene oxide is used as the alkoxylation agent. For economical reasons it has been found that Soya fatty acids are a practical source for this purpose consisting of about 3% myristic acid, about 5% palmitic acid, about 5% palmitoleic acid, 1.5% stearic acid, 72.5% oleic acid and about 13% linoleic acid. Other sources of useful fatty acids are those obtained from the saponification of beef tallow, butter, corn oil, cottonseed oil, lard, olive oil, palm oil, peanut oil, cod liver oil, coconut oil and the like.
A preferred diester quaternary ammonium surfactant fabric softener is methyl bis[ethyl(oleyl)]-2-hydroxyethyl ammonium methyl sulfate. This quaternary ammonium compound is often referred to herein as dioleyl diesterquat (or “DODEQ”).
Other diesters useful in the practice of this invention include:
methyl bis-[ethyl(coconut)]-2-hydroxyethyl ammonium methyl sulfate
methyl bis-[ethyl(decyl)]-2-hydroxyethyl ammonium methyl sulfate
methyl bis-[ethyl(dodecyl)]-2-hydroxyethyl ammonium methyl sulfate
methyl bis-[ethyl(lauryl)]-2-hydroxyethyl ammonium methyl sulfate
methyl bis-[ethyl(palmityl)]-2-hydroxyethyl ammonium methyl sulfate
methyl bis-[ethyl(soft-tallow)]-2-hydroxyethyl ammonium methyl sulfate, and the like.
The designation of the terms coconut and beef tallow indicate mixtures of esters corresponding to the fatty acid source.
In the preparation of the diester quaternary ammonium surfactants, a certain amount of the triester homolog may be produced as an impurity. Unlike the diester, it is not soluble in water and has to be considered as an oil to be emulsified.
The term “oil-based perfume” is used herein in its ordinary sense to refer to and include any non water-soluble fragrant substance or mixture of substances including natural (i.e., obtained by extraction of flower, herb, blossom or plant), artificial (i.e., a mixture of natural oils or oil constituents) and synthetic (i.e., a single or mixture of synthetically produced substance) odoriferous substances. Typically perfumes are complex mixtures of blends of various organic compounds, such as, esters, ketones, hydrocarbons, lactones, alcohols, aldehydes, ethers, aromatic compounds and varying amounts of essential oils (e.g., terpenes) such as from about 0% to about 80%, usually from about 10% to 70% by weight, the essential oils themselves being volatile odoriferous compounds and also serving to dissolve the other components of the perfume. The precise composition of the perfume has no particular effect on fabric softening so long as it meets the criteria of water immiscibility and pleasant odor. The level of perfume in the present softener compositions will generally vary from about 0.1% to about 2.5%, by weight.
The solvents useful for the present invention are selected based on their octanol/water partition coefficient (P). This coefficient is the ratio between the equilibrium concentration of the particular solvent in octanol and in water. The coefficient is commonly provided in the technical literature as the logarithm (to the base 10) of P, namely, log P.
The value of log P of many solvents is often available from the solvent supplier or may be calculated, the “calculated log P” being referred to as C log P. For many solvents, the value of log P is reported and available from Daylight Chemical Information Systems Inc. (Daylight CIS), Irvine, Calif. on the Pomona 92 database. Log P values are also conveniently calculated by the “C log P” program, also available from Daylight CIS. The C log P values are determined based o
Grandmaire Jean-Paul
Hermosilla Anita
Colgate-Palmolive Co.
Hardee John
Lieberman Bernard
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