Multi-layer structure acrylic polymer composition

Stock material or miscellaneous articles – Composite – Of polycarbonate

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428474, 428483, 428515, 428516, 428517, 428518, 428519, 428520, 428522, 260881, 260885, 260883, 260884, 260 296RB, B32B 2736, B32B 2708

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040525252

ABSTRACT:
A multi-layer structure polymer composition composed of an innermost layer (A), an elastomeric layer (B), an outermost layer (C), and at least one intermediate layer, said layer (A) having a glass transition temperature (Tg) of 10.degree. C. or higher and consisting of the reaction product of 51 to 100 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, 0 to 49 parts by weight of a copolymerizable monomer, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent; said layer (B) having a glass transition temperature (Tg) of 0.degree. C. or lower and consisting of the reaction product of 80 to 100 parts by weight of an alkyl acrylate whose alkyl group has 8 or less carbon atoms, 0 to 20 parts by weight of a copolymerizable monomer, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent; said layer (C) having a glass transition temperature (Tg) of 50.degree. C. or higher and consisting of the reaction product of 51 to 100 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, and 0 to 49 parts by weight of a copolymerizable monomer; and said intermediate layer consisting of the reaction product of 10 to 90 parts by weight of an alkyl methacrylate whose alkyl group has 4 or less carbon atoms, 90 to 10 parts by weight of an alkyl acrylate whose alkyl group has 8 or less carbon atoms, 0 to 10 parts by weight of a polyfunctional monomer, and 0.1 to 5 parts by weight of a graftlinking agent. The said polymer composition is excellent in transparency, gloss, and resistance to stress whitening and has good resistance to weather and impact.

REFERENCES:
patent: 3458603 (1969-07-01), Griffin
patent: 3562235 (1971-02-01), Ryan
patent: 3651005 (1972-03-01), Walus
patent: 3681167 (1972-08-01), Moore
patent: 3804925 (1974-04-01), Kato et al.
patent: 3959550 (1976-05-01), Guillod et al.

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