Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Reexamination Certificate
2011-01-11
2011-01-11
Gonzalez, Porfirio Nazario (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
C549S215000, C106S287100
Reexamination Certificate
active
07868198
ABSTRACT:
A multi-functional silsesquioxane, method of making the same, and coatings incorporating the same, including a polyhedral silsesquioxane including at least one first face and at least one second face that is spaced apart from the at least one first face; at least one first functionality bonded to the at least one first face; and at least one second functionality different from the first functionality, and being bonded to the at least one second face. In one particular respect, silica for the silsesquioxane may be derived from rice hull ash via an octa(tetramethylammonium)silsesquioxane octaanion.
REFERENCES:
patent: 5039771 (1991-08-01), Morimoto et al.
patent: 5047492 (1991-09-01), Weidner et al.
patent: 5330734 (1994-07-01), Johnson et al.
patent: 6100417 (2000-08-01), Lichtenhan et al.
patent: 6207364 (2001-03-01), Takamuki et al.
patent: 6329490 (2001-12-01), Yamashita et al.
patent: 6770724 (2004-08-01), Lichtenhan et al.
patent: 6927301 (2005-08-01), Laine et al.
patent: 7256243 (2007-08-01), Oikawa et al.
patent: 2002/0090572 (2002-07-01), Sooriyakumaran et al.
patent: 2003/0120099 (2003-06-01), Laine et al.
patent: 2005/0033077 (2005-02-01), Yamahiro et al.
patent: 2005/0142054 (2005-06-01), Hasegawa et al.
patent: 2006/0040103 (2006-02-01), Whiteford et al.
patent: 2006/0083925 (2006-04-01), Laine et al.
patent: 2006/0122351 (2006-06-01), Laine et al.
patent: 2007/0045619 (2007-03-01), Park et al.
patent: 0736584 (1996-10-01), None
patent: 0736584 (1996-10-01), None
patent: 02-100867 (2002-12-01), None
patent: 03-102695 (2003-12-01), None
patent: 2004-038769 (2004-06-01), None
patent: 2006-132656 (2006-12-01), None
S. Sulaiman, C.M. Brick, C.M. De Sana, J.M. Katzenstein, R.M. Laine, R.A. Basheer,“Tailoring the Global Properties of Nanocomposites. Epoxy Resins with Very Low Coefficients of Thermal Expansion,” Macromolecules 39 5167-9 (2006).
M. Z. Asuncion, R.M. Laine, “Silsesquioxane Barrier Materials,” Macromolecules 40, 555-562 (2007).
http://www.mayaterials.com/html/coatings.html (last accessed Jun. 15, 2007).
C. Brick, E. R. Chan, S.C. Glotzer, D.C. Martin, R.M. Laine, “Self-lubricating nano ball bearings,” Adv. Mater. 19 82-9 (2007).
R. M. Laine, J. Choi, I. Lee, “Organic-Inorganic Nanocomposites with Completely Defined Interfacial Interactions,” Adv. Mater. 13, 800-3 (2001).
C. Zhang, T.J. Bunning, R.M. Laine, “Synthesis and Characterization of Liquid Crystalline (LC) Silsesquioxanes,” Chem. of Mater.; 13; 3653-62 (2001).
J. Choi, J. Harcup, A.F. Yee, Q. Zhu, R.M. Laine, “Organic/inorganic hybrid composites from cubic silsesquioxanes,” J. Am. Chem. Soc. 123, 11420-30 (2001).
R. Tamaki, Y. Tanaka, M. Z. Asuncion, J. Choi, R.M. Laine, “Octa(aminophenyl)silsesquioxane as a Nanoconstruction Site,” J. Am. Chem. Soc. 123, 12416-7 (2001).
R. Tamaki, J. Choi, R.M. Laine “A Polyimide Nanocomposite from Octa(aminophenyl)-silsesquioxane” Chem. Materials 15, 793-7 (2003).
J. Choi, R. Tamaki, S.G. Kim, R.M. Laine, “Organic/Inorganic Imide Nanocomposites from Aminophenylsilsesquioxanes,” Chem. Mater. 15 3365-3375 (2003).
J. Choi, Albert F. Yee, and Richard M. Laine, “Organic/Inorganic Hybrid Composites from Cubic Silsesquioxanes. Epoxy Resins of Octa(dimethylsiloxy-ethylcyclohexylepoxide) Silsesquioxane,” Macromolecules 36, 5666-82 (2003).
J. Choi, A.F. Yee, R.M. Laine, “Toughening of cubic silsesquioxane epoxy nanocomposites using core shell rubber particles; a three component hybrid system,” Macromol. 37, 3267-76 (2004).
M.Z. Asuncion, I. Hasegawa, J. Kampf, R.M. Laine, “The selective dissolution of rice hull ash to form [OSiO1.5]8[R4N]8(R=Me, CH2CH2OH) octasilicates. Basic nanobuilding blocks and possible models of intermediates formed during biosilification processes,” Materials Chemistry 15, 2114-21 (2005).
R.M. Laine, “Nano-building blocks based on the [OSiO1.5]8silsesquioxanes,” J. Mater. Chem., 15, 3725-44 (2005).
N. Takamura, L. Viculis, R.M. Laine “A completely discontinuous organic/inorganic hybrid nanocomposite based on reactions of [HMe2SiOSiO1.5]8with vinylcyclohexene,” International Polymers Journal web published Apr. 16, 2007.
A.R. Bassindale, H. Chen, Z. Liu, I. A. MacKinnon, D. J. Parker, P. G. Taylor, Y. Yang, M. E. Light, P. N. Norton, M. B. Hursthouse,J. Organomet. Chem. 2004, 689, 3287.
A. Sellinger, R.M. Laine, “Silsesquioxanes as Synthetic Platforms. Thermally and Photo Curable Inorganic/Organic Hybrids,” Macromol. 29, 2327-30 (1996).
H.W. Ro, K. Char, E-C. Jeon, H-J. Kim, K. Kwon, H-J. Lee, J-K. Lee, H-W Rhee, C.L. Soles, D.Y. Yoon, “High Modulus Spin-On Organosilicates for Nanoporous Glasses,” Adv. Mater. 19 705-710 (2007).
Liu Zhi—hua, Alan R. Bassindale and Peter G. Taylor, “Synthesis of SilsesquiOxane Cages from Phenyl-cis-tetrol, 1,3-DiVinyltetraethoxydisilOxane and Cyclopentyl Resins,” Chem. Res. Chinese U., 20(4), 433-436 (2004).
J. Chojnowskli, W. Fortuniak, P. Ros' ciszewski, W. Werel, J.img id="CUSTOM-CHARACTER-00001" he="3.13mm" wi="2.12mm" file="US07868198-20110111-P00001.TIF" alt="custom character" img-content="character" img-format="tif" ?ukasiak, W. Kamysz, R. Haimg id="CUSTOM-CHARACTER-00002" he="3.13mm" wi="1.02mm" file="US07868198-20110111-P00002.TIF" alt="custom character" img-content="character" img-format="tif" ?asa, Biocidal Polysilsesquioxanes: “Polysilsesquioxanes and Oligosilsesquioxanes Sub-stituted by Alkylammonium Salts as Antibacterial Biocides” J. Inorganic and Organometallic Poly. and Mater., 16, 219 (2006).
S.P. Denyer, “Mechanisms of Action of Antibacterial Biocides,” International Biodeterioration & Biodegradation (1995) 221-245.
Alan R. Bassindale, Zhihua Liu, Iain A. MacKinnon, Peter G. Taylor, Yuxing Yang, Mark E. Light, Peter N. Horton and Michael B. Hursthouse, “A higher yielding route for T8silsesquioxane cages and X-ray crystal structures of some novel spherosilicates,” Dalton Trans., 2945-2949 (2003).
O. Shchegolikhina, Y. Pozdniakova, M. Antipin, D. Katsoulis, N. Auner, B. Herrschaft, “Synthesis and Structure of Sodium Phenylsiloxanolates,” Organometallics, 19, 1077-82 (2000).
K.A. Andrianov, V.S. Tikhonov, G.P. Makhneva, G.S. Chernov, “Synthesis of Polycyclic Tetramethyltetraphenylcyclooctasilsesesquioxane,” Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 4, 956-957 (1973).
A. Sellinger, R.M. Laine, “Silsesquioxanes as Synthetic Platforms. III. Photocurable, Liquid Epoxides as Inorganic/Organic Hybrid Precursors,” Chem. Mater. 8, 1592-3 (1996).
R. M. Laine, M. Roll, M. Asuncion, S. Sulaiman, V. Popova, D. Bartz, D. J. Krug, P. H. Mutin, “Perfect and nearly perfect silsesquioxane (SQs) nanoconstruction sites and Janus SQs,” Journal of Sol-Gel Science and Technology, 46, 335-347 (2008).
M.G. Voronkov et al., “Polyhedral Oligosilsesquioxanes and their Homo Derivatives”, Top. Curr. Chem., 102, 199-236 (1982).
R.Q. Su, T.E. Muller, J. Prochazka, J.A. Lercher, “A New Type of Low-k Dielectric Films Based on Polysilsesquioxanes,” Adv. Mater. 14, 1369-73 (2002).
K. Takahashi, S. Sulaiman, J. Katzenstein, S. Snoblen, R. Laine, “New Aminophenylsilsesquioxanes—Synthesis, Properties and Epoxy Nanocomposites”, Aust. J. Chem., 59, 564-570 (2006).
C. Zhang, F. Babonneau, C. Bonhomme, R. Laine, C. Soles, H. Hristov, A. Yee, “Highly Porous Polyhedral Silsesquioxane Polymers. Synthesis and Characterization,” J. Am. Chem. Soc. ,120, 8380-8391 (1998).
J. Choi, J. Harcup, A.Yee, Q. Zhu, R. Laine, “Organic/Inorganic Hybrid Composites from Cubic Silsesquioxanes,” J. Am. Chem. Soc., 123, 11420-11430 (2001).
S.G. Kim, J. Choi, R. Tamaki, Richard M. Laine, “Synthesis of amino-containing oligophenylsilsesquioxanes,” Polymer, 46, 4514-4524, (2005).
Jiwon Choi, Seung Gyoo Kim, and Richard M. Laine,
Asuncion Michael Z.
Bartz Daniel W.
Krug, III David J.
Laine Richard M.
Popova Vera
Gonzalez Porfirio Nazario
Kubotera & Associates LLC
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