Multi-dentate late transition metal catalyst complexes and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S172000

Reexamination Certificate

active

06864334

ABSTRACT:
The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1through C12alkyl, C1through C12alkoxy, C3through C12cycloalkyl, C3through C12cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1through C12alkyl, C1through C12alkoxy, C3through C12cycloalkyl, C3through C12cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.

REFERENCES:
patent: 6037297 (2000-03-01), Stibrany et al.
patent: 6417303 (2002-07-01), Stibrany et al.
patent: 6479425 (2002-11-01), Stibrany et al.
patent: WO 9930822 (1999-06-01), None
patent: WO 0035974 (2000-06-01), None
Davis et al., Macromolecules, vol. 33, No. 11, pp. 4039-4047 (2000).

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