Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2011-08-23
2011-08-23
Lu, Caixia (Department: 1765)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S160000, C526S165000, C526S348000, C526S943000
Reexamination Certificate
active
08003739
ABSTRACT:
Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpAand CpBeach denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpAand CpBeach denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
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Blackmon Kenneth P.
Coffy Tim J.
Daumerie Michel
Gauthier William J.
Thorman Joseph L.
Fina Technology, Inc.
Lu Caixia
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