Monosaccharides and products resulting therefrom

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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2603436, 2603473, 424180, 424279, 536 4, 536118, 536119, 536120, C07H 302, C07H 902

Patent

active

041339487

ABSTRACT:
The invention provides novel compounds of the formula: ##STR1## wherein B is .alpha.- or .beta.- and represents a hydrocarbyl group in which the .alpha.-carbon atom is activated by a suitable blocked or unblocked functional group rendering it susceptible to oxidation. The compounds are useful as intermediates in the preparation of prostaglandins and prostaglandin analogues. The invention also provides a stereospecific method of producing these intermediates.

REFERENCES:
patent: 3297604 (1967-01-01), Germino
patent: 3592808 (1971-07-01), Theander
patent: 3632802 (1972-01-01), BeMiller et al.
House "Modern Synthetic Reactions", 2nd Ed., W. A. Benjamin, Inc., Menlo Park, Calif., 1972, pp. 562-563.
Solomons "Organic Chemistry", John Wiley & Sons, Inc., New York, N.Y., 1976, pp. 710-714.

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