Monomers and oligomers containing a plurality of vinylbenzyl eth

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568 33, 568 36, 568 37, 568 49, 568333, 568645, 568646, 526286, 526333, C07C14912

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047075589

ABSTRACT:
Monomers and oligomers containing a plurality of vinylbenzyl ether groups are prepared by reacting a material containing a plurality of aromatic hydroxyl groups such as tetramethyltetrabromobisphenol A with a vinylbenzyl halide such as vinylbenzyl chloride in the presence of a polar aprotic solvent such as dimethylformamide. The monomers and oligomers prepared by this process have an improvement in one or more properties selected from dielectric constant (before and/or after moisture absorption) or thermal stability. Also disclosed are new monomers and oligomers containing a plurality of vinylbenzyl ether groups such as bis(vinylbenzyl)ether of dicyclopentadienyl bisdimethylphenol.

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