Monomeric thioloesterification of 1,3-alkadiene

Details Monomeric thioloesterification of 1,3-alkadiene Monomeric thioloesterification of 1,3-alkadiene

1981-12-14

1986-04-22

Jiles, Henry R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Esters having the thiocarboxylate group, -cx-, wherein the...

C07C15301

Patent

active

045841446

ABSTRACT:
This invention provides a process for monomeric thioloesterification of 1,3-alkadiene in the presence of a catalyst which is a stabilized complex of palladium, tertiary phosphine ligand and thiol compound.
Monomeric thioloesterification of 1,3-butadiene with 1-butanethiol and carbon monoxide in accordance with the present invention process provides a high conversion and selectivity yield of 1-butyl 3-thiolopentenoate product.

REFERENCES:
patent: 3933884 (1976-01-01), Knifton

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