Monomeric organometallic compounds and method of preparing same

Details Monomeric organometallic compounds and method of preparing same Monomeric organometallic compounds and method of preparing same

1990-06-08

1991-11-26

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 30, 556 64, 556 70, 556174, 556176, C07F 900, C07F 500

Patent

active

050683705

ABSTRACT:
Preparation of the novel monomeric compounds of the formula (t-Bu).sub.2 ME(t-Bu).sub.2, where M is Ga, Al, or In and E is As, P, Sb, or N, by reaction of (t-Bu).sub.2 MCl and LiE(t-Bu).sub.2. The resulting product (t-Bu).sub.2 ME(t-Bu).sub.2 can be pyrolyzed to form crystalline films of the metallic material, ME.

REFERENCES:
patent: 3320296 (1967-05-01), Fetter et al.
Pitt et al., Organometallics, vol. 5, pp. 1266-1268, 1986.
Schram et al., Inorganica Chemica Acta, vol. 113, pp. 131-135, 1986.
Overman et al., Tetrahedron Letters, vol. 22, pp. 195-198, 1981.
Kelvin T. Higa and Clifford George, "(t-Bu).sub.2 GaAs(t-Bu).sub.2 : A Voile Monomeric Aisinogallane", Organometallics, vol. 9, No. 1, pp. 275-277, 1990.

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