Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound
Reexamination Certificate
2007-01-09
2007-01-09
Le, H. Thi (Department: 1773)
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
C423S022000, C423S023000, C423S024000, C423S138000, C423S139000
Reexamination Certificate
active
10965685
ABSTRACT:
Nanoparticle compositions of noble metals, and methods of making them, are described. The nanoparticle compositions are made by reacting a salt or complex of a noble metal, such as Au, Ag, Cu or Pt, with a weak ligand, and a reducing agent, in a single liquid phase. The noble metal is typically provided as a halide or carboxylate. The ligand is preferably a fatty acid or aliphatic amine. The reducing agent is preferably a borohydride reagent, hydrazine, or a mixture thereof. Nanocrystals in the size range of 1 nm to 20 nm are produced, and can be made in substantially monodisperse form.
REFERENCES:
patent: 6103868 (2000-08-01), Heath et al.
patent: 6262129 (2001-07-01), Murray et al.
patent: 6379635 (2002-04-01), O'Brien et al.
patent: 6572673 (2003-06-01), Lee et al.
patent: 6645444 (2003-11-01), Goldstein
patent: 6872249 (2005-03-01), Peng et al.
patent: 2002/0066401 (2002-06-01), Peng et al.
patent: 2004/0089101 (2004-05-01), Winter et al.
patent: 2004/0101976 (2004-05-01), Peng et al.
Brust, M., et al., “Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system,”JCS, Chem. Comm., 1994, 801-802.
Collier, C., et al., Reversible tuning of silver quantum dot monolayers through the metal-insulator transition,Science, 1997, 277:1978-1981.
Leff, D. et al., “Synthesis and characterization of hydrophobic, organically-soluble gold nanocrystals functionalized with primary amines,”Langmuir, 1996, 12: 4723-4730.
Cliffel, D. et al., “Mercaptoammonium-monolayer-protected, water-soluble gold, silver, and palladium clusters,”Langmuir, 2000, 16: 9699-9702.
Turkevich, J. et al., “A study of the nucleation and growth processes in the synthesis of colloidal gold,”Disc. Faraday Soc.1951, 11: 55-75.
Wallenberg, L. R., et al., “On the crystal structure of small gold crystals and large gold clusters,”Surf. Sci., 1985, 156: 256-64.
Teranishi, T., et al., “Synthesis of monodisperse gold nanoparticles using linear polymers as protective agents,”Adv. Mater., 1998, 10: 596-599.
Green, M., et al., “A simple one phase preparation of organically capped gold nanocrystals,”Chem. Commun.,2000, 183-184.
Stoeva, S., et al., “Gram-scale synthesis of monodisperse gold colloids by the solvated metal atom dispersion method and digestive ripening and their organization into two- and three-dimensional structures,”JACS, 2002, 124: 2305-2311.
Murphy, C., et al., “Controlling the aspect ratio of inorganic nanorods and nanowires,”Adv. Mater., 2002, 14: 80-82.
Brown, L. et al., “Controlled growth of gold nanoparticles during ligand exchange,”JACS, 1999, 121:882-883.
Zhong, C. et al., “Size and shape evolution of core-shell nanocrystals,”Chem. Commun., 1999, 1211-1212.
Lin, X. et al., “Digestive ripening, nanophase segregation and superlattice formation in gold nanocrystal colloids,”J. Nanopart. Res., 2000, 2:157-164.
Shimizu, T., et al., “Size evolution of alkanethiol-protected gold nanoparticles by heat treatment in the solid state,”J. Phys. Chem. B, 2003, 107:2719-2724.
Ahmadi, T. et al., “Shape-controlled synthesis of colloidal platinum nanoparticles,”Science, 1996, 272: 1924-1926.
Watzky, M., et al., “Transition metal nanocluster formatin kinetic and mechanistic studies. A new mechanism when hydrogen is the reductant: slow, continuous nucleation and fast autocatalytic surface growth,”JACS, 1997, 119: 10382-10400.
Courty, A., et al., “Supra Crystals made of nanocrystals,”Adv. Mater., 2001, 13: 254-258.
Ziegler, K., et al., “Synthesis of organic monolayer-stabilized copper nanocrystals in supercritical water,”JACS, 2001, 123: 7797-7803.
Filankembo, A., et al., “Is the anion the major parameter in the shape control of nanocrystals?”J. Phys. Chem. B, 2003, 107: 7492-7500.
Murray, C., et al., “Synthesis and characterization of nearly monodisperse CdE (E=S, Se, Te) semiconductor nanocrystallites,”JACS, 1993, 115: 8706-8715.
Peng, X., et al., “Kinetics of II-VI and III-V colloidal semiconductor nanocrystal growth: “Focusing” of size distributions,”JACS, 1998, 120: 5343-5344.
Peng, Z. et al, “Formation of high-quality CdTe, CdSe, and CdS nanocrystals using CdO as precursor,”JACS, 2001, 123: 183-184.
Qu, L., et al., “Alternative routes toward high quality CdSe nanocrystals,”Nano Lett., 2001, 1: 333-337.
Yu, W. et al., “Formation of High-quality CdS and other II-VI semiconductor nanocrystals in noncoordinating solvents: tunable reactivity of monomers,”Angew. Chemie Int. Ed., 2002, 41: 2368-2371.
Yu, W. et al., “Experimental determination of the extinction coefficient of CdTe, CdSe, and CdS nanocrystals,”Chem. Mater., 2003, 15: 2854-2860.
Jana Nikhil
Li Lin Song
Peng Xiaogang
Le H. Thi
Meadows James H.
Medicus Associates
The Board of Trustees of the University of Arkansas
LandOfFree
Monodisperse noble metal nanocrystals does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Monodisperse noble metal nanocrystals, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Monodisperse noble metal nanocrystals will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3778477