Monocyclopentadienyl complex

Details Monocyclopentadienyl complex Monocyclopentadienyl complex

2003-08-11

2009-06-02

Lu, Caixia (Department: 1796)

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

C526S160000, C526S161000, C526S169000, C526S170000, C502S152000, C502S167000

Reexamination Certificate

active

07541481

ABSTRACT:
Monocyclopentadienyl complexes in which the cyclopentadienyl system bears at least one unsubstituted, substituted or fused, heteroaromatic ring system bound via a specific bridge, a catalyst system, comprising at least one of these monocyclopentadienyl complexes, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system and polymers obtainable therewith.

REFERENCES:
patent: 3242150 (1966-03-01), Scoggin
patent: 3248179 (1966-04-01), Norwood
patent: 3709853 (1973-01-01), Karapinka
patent: 4015059 (1977-03-01), Karol
patent: 5547675 (1996-08-01), Canich
patent: 5698642 (1997-12-01), Govoni et al.
patent: 5808122 (1998-09-01), Herrmann et al.
patent: 5955555 (1999-09-01), Bennett
patent: 5986029 (1999-11-01), van Beck et al.
patent: 6087291 (2000-07-01), Speca et al.
patent: 6214761 (2001-04-01), Bennett
patent: 6255246 (2001-07-01), Devore et al.
patent: 6255418 (2001-07-01), Jolly et al.
patent: 6284905 (2001-09-01), Ashe, III et al.
patent: 6297338 (2001-10-01), Cotts et al.
patent: 6365779 (2002-04-01), Devore et al.
patent: 6376406 (2002-04-01), Ashe, III et al.
patent: 6413477 (2002-07-01), Govoni et al.
patent: 6417302 (2002-07-01), Bohnen
patent: 6417305 (2002-07-01), Bennett
patent: 6423848 (2002-07-01), Bennett
patent: 6444606 (2002-09-01), Bingel et al.
patent: 6492539 (2002-12-01), Bingel et al.
patent: 6548442 (2003-04-01), McDaniel et al.
patent: 6589905 (2003-07-01), Fischer et al.
patent: 6723675 (2004-04-01), Wang
patent: 6756505 (2004-06-01), Kristen et al.
patent: 6784261 (2004-08-01), Schopf et al.
patent: 7238818 (2007-07-01), Ewen et al.
patent: 2001/0000519 (2001-04-01), Bennett
patent: 2001/0007044 (2001-07-01), Devore et al.
patent: 2001/0025115 (2001-09-01), Campbell, Jr. et al.
patent: 2002/0007034 (2002-01-01), Cotts et al.
patent: 2002/0013431 (2002-01-01), Bennett
patent: 2002/0058584 (2002-05-01), Bennett et al.
patent: 2002/0061264 (2002-05-01), Govoni et al.
patent: 2002/0072578 (2002-06-01), Wu et al.
patent: 2002/0086957 (2002-07-01), Wu et al.
patent: 2002/0132945 (2002-09-01), Wu et al.
patent: 2003/0009046 (2003-01-01), Bingel et al.
patent: 2003/0171511 (2003-09-01), McDaniel et al.
patent: 2003/0199650 (2003-10-01), Devore et al.
patent: 2003/0236164 (2003-12-01), Fischer et al.
patent: 2004/0002420 (2004-01-01), Wu et al.
Theopald et al. “Constrained Geometry Chromium Catalysts for Olefin Polymerization”, Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, Delaware 19716, 15, 5284-5286, (1996).
Lettau et al. “Chemie der Heterocyclen”, 1stEdition, Weinheim, VEB (1979).
Jutzi et al. “Cyclopentadienyl compounds with nitrogen donors in the side-chain”, Fakultät für Chemie der Universität Bielefeld, 500, S. 175-185, Sec. 3, (1995).
Enders et al. “8-Quinolylcyclopentadienyl, a Ligand with a Tailored Fit for Chelate Complexes”, Anorganisch-Chemisches Institut der Universität, 129, S. 459-463, (1996).
Blais et al. “Pendent Aminoalkyl-Subsituted Monocyclopentadienyltitanium Compounds and Their Polymerization Behavior”, Department of Chemistry, University of Massachusetts, Amherst Massachusetts 01003 (1998), 17—S. 3775-3783.
Kirk-Othmer, B. “High Pressure (Low and Intermediate Density) Polyethylene” in ECT 2nded., under “Olefin Polymers,” vol. 14, pp. 217-241, by P. L. Clegg, Imperial Chemical Industries Ltd., Encyclopedia of Chemical Technology, 1981, vol. 16, S. 402.
Halterman et al. “Synthesis and Applications of Chiral Cyclopentadienylmetal Complexes”, Department of Chemistry and Biochemistry, -92, 1992, S. 965-994, (1992).
Strauss et al. “The Search for Larger and Mire Weakly Coordinating Anions”, Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523 (1993), S. 927-942.
Ewen et al. “Expanding the Scope of Metallocenes Catalysis: Beyond Indenyl and Fluorenyl Derivatives”, Catalyst Research Corporation, Springer Verlag (1999), S. 150 ff.
Braunschweig et al. “The chemistry of [1]borametallocenophanes and related compounds”, Insitut für Anorganische Chemie der Universität Würzburg, vol. 680, ro.1-2, 2003, S. 31-42 (2003).
Duchateau et al. “Synthesis of Cyclopentadienyl-, Indenyl-, and Fluorenylbis (pentafluorophenyl)boranes as Ligands in Titanium and Zirconium Half-Sandwich Complexes. The Crystal Structures of . . . ”, School of Chemistry, University of Leeds, LS2 9JT Leeds, United Kingdom, 16 (23), S. 4995-5005 (1997).
Zi et al. “Synthesis, Structural Characterization, and Catalytic Property of Groups 4 Metal Carborane Compounds with a . . . ”, Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China 21 (19), S. 3850-3855 (2002).
Hartwig et al. “Structural and Reaction Chemistry of Tungstenocene Boryl Complexes”, Department of Chemistry, Yale University, New Haven 15 (25) S. 5350-5358 (1996).
Frieser et al. Frieser+Frieser, 3rd—“Lehrbuch der Organischen Chemie—Heterocyclen” (1957); revised ed., Weinheim (1957).
Wiesenfeldt et al. “XVII—Racemic and meso diastereomers of group IV metallocene . . . ”, Fakultät für Chemie, Universität Konstanz, Journal of Organometallic Chemistry 369, 1989, S. 359-370 (1989).
Small et al. “Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene”, Department of Chemistry, University of North Carolina (1998); J.Am. Chem.Soc. 120, S. 4049ff, (1998).
Britovsek et al. “Novel olefin polymerization catalysts based on iron and cobalt”, Department of Chemistry Imperial College, Exhibition Road, South Kensington, London (1998); J. Chem. Soc., Chem. Commun., 1998, S. 849.
Cervantes et al. Large-scale dynamic optimization of a low density polyethylene plant:, Chemical Engineering Department, Carnegie Mellon University, Pittsburg, PA 15213 (2000).
Döhring, et al., “Donor-Ligand-Substituted Cyclopentadienylchromium (III) Complexes: A New Class of Alkene Polymerization Catalyst. 1. Amino-Substituted Systems”,Organometallics 19(2000) 392.

Affiliated with

Also associated with

Rating

Monocyclopentadienyl complex does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Monocyclopentadienyl complex, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Monocyclopentadienyl complex will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-4136312