Molybdenum phosphate compositions

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 24, 556 13, 556 57, 556 64, 423302, 423305, 423306, 423308, C07F 900, C07F 1100, C07F 970

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051170191

ABSTRACT:
A class of new oxide structures containing octahedral molybdenum and tetrahedral phosphorous has been generated using hydrothermal techniques. These materials are produced by the reaction of a molybdenum oxide source with phosphate and any one, or combination of organic cation/alkali-metal cation/organic amine as a templating/mineralizing agent. A reducing agent is necessary to convert the Mo(VI) to a lower valent form and can be either added to the reaction mixture or is provided in the form of one of the reactants.

REFERENCES:
patent: 4440871 (1984-04-01), Lok et al.
patent: 4544143 (1985-10-01), Cooper et al.
patent: 4956483 (1990-09-01), Corcoran, Jr. et al.
Wilson et al., J. Am. Chem. Soc., vol. 104, pp. 1146-1147 (1982).
Lok et al., J. Am. Chem. Soc., vol. 106, pp. 6092-6093 (1984).

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