Molybdenum-exchanged crystalline aluminosilicate zeolite

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252439, 423112, B01J 2916, B01J 2926, B01J 2936

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active

043882242

ABSTRACT:
Molybdenum is ion exchanged into a crystalline aluminosilicate zeolite, replacing metals such as sodium, calcium, and potassium, by contacting the zeolite with an aqueous solution containing molybdenyl cations (i.e., MoO.sub.2.sup.2+) and having a pH below 7.0 but higher than that which would substantially affect the crystallinity of the zeolite. The resulting zeolite, when calcined or sulfided, is useful as a catalyst for hydrocarbon conversion reactions, particularly with respect to the hydrodealkylation of toluene to benzene and methane.

REFERENCES:
patent: 3013988 (1961-12-01), Bukata et al.
patent: 3308069 (1967-03-01), Wadlinger et al.
patent: 3794598 (1974-02-01), Schlaffer
patent: 3839228 (1974-10-01), Kirsch
patent: 3875081 (1975-04-01), Young
patent: 3959179 (1976-05-01), Mikovsky et al.
Climax Molybdenum Company of Michigan, Document No. L-287-34, dated Nov. 19, 1976, Entitled "Preparation and Characterization of Zeolites Containing Exchanged Molybdenum" by Tsigdinos et al.
"Catalytic Properties of Molybdenum Zeolites in Epoxidation of Cyclohexene" by Dai et al., A Catalysis Society Meeting, Mar. 18-22, 1979, Chicago, Ill.

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