Molybdenum catalyzed oxidative coupling polymerization of arenes

Details Molybdenum catalyzed oxidative coupling polymerization of arenes Molybdenum catalyzed oxidative coupling polymerization of arenes

1974-06-24

1977-05-10

Briggs, Sr., Wilbert J.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

260670, C08G 6110

Patent

active

040227170

ABSTRACT:
Arene polymers can be made by oxidative coupling of arenes of at least 10 carbons, optionally with benzene, using liquid hydrogen fluoride, a catalytic amount of a molybdenum compound and oxygen as the oxidant.

REFERENCES:
patent: 3386899 (1968-06-01), Shepard et al.
patent: 3480568 (1969-11-01), Weichman et al.
"Polymerization of Benzene to p-Polyphenyl by Molybdenum Pentachloride", Kovacic, P. et al., J. Organic Chem. vol. 28, April 1963, pp. 968-972.

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