Molybdenum and tungsten peroxo complexes useful as oxidation cat

Details Molybdenum and tungsten peroxo complexes useful as oxidation cat Molybdenum and tungsten peroxo complexes useful as oxidation cat

1979-05-18

1981-03-31

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568342, 568385, C07C 4529

Patent

active

042595274

ABSTRACT:
A catalytic system for oxidation of organic compounds including olefins, cyclic ketones and secondary alcohols. Soluble peroxo or solid supported oxo or peroxo complexes of molybdenum or tungsten are used in the presence of hydrogen peroxide to effect the oxidation. The resulting products include lactones, hydroxy acids, ketoacids, hydroxy esters and ketoesters from cyclic ketones; ketones from secondary alcohols and polyols or derivatives thereof from allylic alcohols.

REFERENCES:
patent: 3098100 (1963-07-01), Freure
patent: 3156709 (1964-11-01), Allan et al.
patent: 3235602 (1966-02-01), Russell
patent: 3671591 (1972-06-01), Schwager et al.
Beiles et al, Russian J. of Inorg, Chem., vol. 12, pp. 467-470 (1967).
Westlake et al, C.R. Acad. Sc. Paris, #280 pp.113-115 (1975).

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