Molybdenum and tungsten peroxo complexes useful as oxidation cat

Details Molybdenum and tungsten peroxo complexes useful as oxidation cat Molybdenum and tungsten peroxo complexes useful as oxidation cat

1977-10-14

1979-10-16

Trousof, Natalie

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603435, 260586P, 260596, 546 5, 560179, 562579, 568860, 423584, 252430, 252431C, C07D30930, C07D31304, C07C 6966, C07C 5904

Patent

active

041713133

ABSTRACT:
A catalytic system for oxidation of organic compounds including olefins, cyclic ketones and secondary alcohols. Soluble peroxo or solid supported oxo or peroxo complexes of molybdenum or tungsten are used in the presence of hydrogen peroxide to effect the oxidation. The resulting products include lactones, hydroxy acids, ketoacids, hydroxy esters and ketoesters from cyclic ketones; ketones from secondary alcohols and polyols or derivatives thereof from allylic alcohols.

REFERENCES:
patent: 3428656 (1969-02-01), Weiss et al.
patent: 3584011 (1971-06-01), Weiss et al.
patent: 3681395 (1972-08-01), Mookherjee
patent: 3728358 (1973-04-01), Mookherjee
patent: 3833613 (1974-09-01), Field et al.
Fieser & Fieser, pp. 456-467, John Wiley and Sons Inc.

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