Molten salt hydroconversion process

Mineral oils: processes and products – Products and compositions – Lubricating oils

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208 8, 208108, C10G 108

Patent

active

040922367

ABSTRACT:
Hydrocarbonaceous materials such as petroleum residuums, coal, lignite or the like are introduced into a molten salt bath maintained in a reaction zone at elevated temperature and pressure. Hydrogen also is introduced into the reaction zone in an amount sufficient to provide a pressure in the reaction zone within the range of from about 30 to 400 atmospheres. The hydrocarbonaceous material is reacted for a time sufficient to produce cracked products including a major amount of liquid and a minor amount of gaseous and solid products of enriched hydrogen content. The molten salt bath comprises at least one alkali metal hydroxide which preferably is sodium hydroxide. Substantially all of the sulfur and ash constituents of the hydrocarbonaceous material are retained in the molten salt. When the hydrocarbonaceous material is a normally solid material such as coal, it advantageously is crushed and slurried in an organic hydrogen donor solvent prior to its introduction into the molten salt bath.

REFERENCES:
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patent: 3677932 (1972-07-01), Hardesty et al.
patent: 3679577 (1972-07-01), Wantland et al.
patent: 3708270 (1973-01-01), Birk et al.
patent: 3745109 (1973-07-01), Heredy et al.
patent: 3779722 (1973-12-01), Tatum
patent: 3966582 (1976-06-01), Cramer
patent: 4003823 (1977-01-01), Baird et al.

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