Molten carbonate cathodes and method of fabricating

Chemistry: electrical current producing apparatus – product – and – Having earth feature

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502328, 502330, 502337, H01M 486, B01J 2358, B01J 2300

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active

047089172

ABSTRACT:
Molten carbonate fuel cell cathodes formed from a composition comprising oxides of nickel, lithium salts and barium salts having improved strength. These cathodes are fabricated by prefiring oxides of nickel and optionally lithium salts. The prefired powder is optionally leached with an organic acid and optional barium salts may be added. These powders are formed into an electrode and sintered. The resulting electrodes have improved strength.

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"Time Dependence of NiO-Li.sub.2 O Solid Solution Formation", by Yoshio Iida-Journal of the American Ceramic Society-Discussion and Notes, Jan. 1960.
CA Selects-Batteries & Fuel Cells, Issue 26, 1983, p. 6, Abstract 99:215827e, Molten-Carbonate Fuel-Cell Cathode.
"Fuel Cells With Molten-Carbonate Electrolytes", by H. A. Liebhafsky and E. J. Cairns, J. Wiley, Capter 12, Fuel Cells with Molten-Carbonate Electrolytes, pp. 524-553.
Argonne National Laboratory Paper ANL-79-55, "Critical Survey on Electrode Aging in Molten Carbonate Fuel Cells", by K. Kinoshita-Dec. 1979.

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