Molecular weight regulation of cis-1,4-polybutadiene using carbo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 84, 5261243, 5261253, 5261258, 526137, 526213, 526216, 5263404, C08F 238, C08F13606

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059555530

ABSTRACT:
There is disclosed a process for the regulation of the molecular weight of high cis polybutadiene prepared by polymerizing butadiene under solution polymerization conditions employing as the catalyst system a mixture of (a) organoaluminum compounds; (b) organonickel compounds; and (c) fluorine containing compounds; said polymerization being conducted in the presence of alkali or alkaline earth metal salts of organic carboxylic acids.

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