Stock material or miscellaneous articles – Composite – Of quartz or glass
Patent
1992-08-21
1994-02-15
Robinson, Ellis P.
Stock material or miscellaneous articles
Composite
Of quartz or glass
428405, 428406, 428410, 428429, 428446, 428447, 429212, 429218, B32B 1706
Patent
active
052865711
ABSTRACT:
This invention relates to a molecular modification reagent consisting of an inorganic oxide substrate having surface oxygens bonded to silylcobalt tetracarbonyl groups. This reagent is functionalized to form new compounds useful e.g., in semi-conductor industry, sensor industry, chromatography and modified support industry, and in the isolation of biologically active molecules.
REFERENCES:
patent: 4198467 (1980-04-01), Reade
patent: 4761316 (1988-08-01), Ogawa
patent: 4835269 (1989-05-01), Kohavec et al.
patent: 4992300 (1991-02-01), Ogawa
patent: 5057339 (1991-10-01), Ogawa
patent: 5130189 (1992-07-01), Hart
Nuzzo, et al. "Fundamental Studies of Microscopic Wetting on Organic Surfaces, 1, Formation and Structural Characterization of a Self-Consistent Series of Polyfunctional Organic Monolayers" J. Amer. Chem. Soc. 112:558-69 (1990).
Porter, et al. "Spontaneously Organized Molecular Assemblies. 4. Structural Characterization of n-Alkyl Thiol Monolayers on Gold by Optical Ellipsometry, Infrared Spectroscopy, and Electrochemistry" J. Amer. Chem. Soc. 109:3359-68 (1987).
Rubenstein, et al. "Ionic Recognition and Selective Response in Self-Assembling Monolayer Membranes on Electrodes" Nature 332: 426-429 (1988).
Little, et al. "Amides of Ferrocenemonocarboxylic Acid. A Convenient Method for Preparing Ferrocenemonocarboxylic Acid and Heteroannular Substituted Derivatives" J. Amer. Chem. Soc. 82:1577-80 (1960).
Little, et al. "Ferrocenylazobenzenes. Resonance Interaction of Ferrocene with Substrates" Organic Chemistry 25:1979-82 (1960).
Mirkin, et al. "Chemically Sensitive Microelectrochemical Devices: New Approaches to Sensors" Amer. Chem. Soc. 17:218-36 (1992).
Hickman, et al. "Selective Functionalization of Gold Microstructures Ferrocenyl Derivatives via Reaction with Thiols or Disulfides: Characterization by Electrochemistry and Auger Electron Spectroscopy" J. Amer. Chem. Soc. 113:1128-32 (1991).
Chalk, et al. "Reactions Between Dicobalt Octacarbonyl and Silicon Hydrides" J. Amer. Chem. Soc. 87:1133-35 (1965).
Chidsey, et al. "Molecular Order at the Surface of an Organic Monolayer Studies by Low Energy Helium Diffraction" J. Chem. Phys. 91:4421-23 (1989).
Finklea, et al. "Passivation of Pinholes in Octadecanethiol Monolayers on Gold Electrodes by Electrochemical Polymerization of Phenol" Langmuir 6:371-76 (1990).
Baay, et al. "Trimethyl-and Trichlorosilylcobalt Tetracarbonyls and the Hydrosilation of Ethylene" Inorganic Chemistry 8:986-994 (1969).
Bain, et al. "Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto Gold" J. Amer. Chem. Soc. III:321-335 (1989).
Bain, et al. "Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Head Group, Tail Group, and Solvent" J. Amer. Chem. Soc. III:7155-64 (1989).
Strong, et al. "Structures of Self-Assembled Monolayer Films of Organosulfur Compounds Absorbed on Gold Single Crystals: Electron Diffraction Studies" Langmuir 4:546-58 (1988).
Wrighton, et al. "Preparation of Chemically Derivatized Platinum and Gold Electrode Surfaces, Synthesis, Characterization, and Surface Attachment of Trichlorosilylferrocene, (1,1'-Ferrocenediyl)dichlorosilane, and 1,1'-bix(triethoxysilyl)ferrocene" J. Amer. Chem. Soc. 100: 7264-71 (1978).
"Dicobalt Octocarbonyl as a Catalyst . . . ", Harrod, Chalk, JACS, 87, 1133, 1965.
"Covalently attached Organic Monolayers on Semicon. Surfaces", Haller, JACS, 100:26, 8050-55, 1978.
"Preparation of Chem. Derivatized Platinum and Gold Electrode Surfaces", Wrighton, JACS, 100:23,7264, 1978.
"Covalent Attachment of Arenes to SnO.sub.2 -semiconductor electrodes", Fox, JACS, 102:12, 4029-36, 1980.
Chen Kaimin
Mirkin Chad A.
Northwestern University
Robinson Ellis P.
Speer Timothy M.
LandOfFree
Molecular modification reagent and method to functionalize oxide does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Molecular modification reagent and method to functionalize oxide, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Molecular modification reagent and method to functionalize oxide will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1205716