Molded articles of syndiotactic polypropylene and method for pre

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263482, 5263485, 5263484, 526160, 428332, C08F 1006

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active

055918174

ABSTRACT:
A molded article of a syndiotactic polypropylene having excellent transparency in which a melting point attributed to the polypropylene having the syndiotactic structure measured at a heating rate of 10.degree. C./minute by differential scanning thermal analysis is represented by a substantially single peak, the aforesaid molded article being prepared by heating, melting and then hot-molding a homopolymer of propylene or a copolymer of propylene and a small amount of another olefin, which have a substantially syndiotactic structure, or a mixture of the homopolymer or the copolymer and a small amount of a polypropylene having a substantially isotactic structure, followed by quenching, or, after these steps, additionally subjecting the above molded article to a heat treatment at a temperature of less than its melting point. A method for preparing the above molded article is also disclosed here.

REFERENCES:
patent: 3258455 (1966-06-01), Natta et al.
patent: 3361728 (1968-01-01), Coen et al.
patent: 4892851 (1990-01-01), Ewen et al.
J. Am. Chem. Soc. 1988, 110, pp. 6255-6256.
World Patent Index Latest, Section Ch. Week 40, Derwent Publications Ltd., London, GB; Class A, AN 83-779353 & JP-A-58 142 818 (Idemitsu Petrochem) Aug. 25, 1983.
World Patent Index Latest, Section Ch. Week 40, Derwent Publications Ltd., London, GB; Class A, AN 86-261852 & JP-A-61 189 920 (Idemitsu Petrochem) Aug. 23, 1986.
Puff et al, Crystalline Olefin Polymer, Pt. II, Interscience Publ. N.Y. vol. XX, (1964) p. 209.

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