Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And group iii or rare earth metal or lanthanide containing
Patent
1995-02-08
1996-11-19
Straub, Gary P.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And group iii or rare earth metal or lanthanide containing
502 79, 502208, B01J 2100
Patent
active
055762581
ABSTRACT:
A process for preparing a modified Y-zeolite, in which a NaY-zeolite is first subjected to an ammonium exchange, the resulting ammonium-exchanged zeolite is subjected to an aluminum exchange, the aluminum-exchanged zeolite is subjected to a steam calcination, and a phosphorus component is incorporated into the steam calcined zeolite, is disclosed. The modified Y-zeolite obtained by this process and an FCC catalyst containing the modified Y-zeolite are also disclosed. The FCC catalyst containing the aluminum-exchanged phosphorus-containing Y-zeolite prepared according to the present invention shows less coke make, and an improved selectivity to C.sub.3 olefins compared to FCC catalysts containing zeolites which have either been aluminum exchanged or contain phosphorus.
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Canos Avelino C.
Chamberlain Oscar R.
Souza-Aguiar Eduardo F.
Dunn Jr. Thomas G.
Morris Louis A.
Noto Joseph M.
Petroleo Brasileiro S.A. - Petrobras
Straub Gary P.
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