Modified polyorganosiloxane containing isocyanate group and proc

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 13, 528 15, 528 18, 528 19, 528 21, 528 23, 556414, 556420, C08G 7704

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active

048228508

ABSTRACT:
There is here provided a modifier for a resin containing an active hydrogen capable of reacting with an isocyanate group. The modifier of the present invention can give characteristics such as low frictional properties, water repellency, oil repellency and antithrombotic properties to the resin, and when the modifier of the present invention is used, neither bleeding phenomenon nor deterioration in mechanical strength takes place.
The present modifier comprises a modified polyorganosiloxane containing an isocyanate group which is represented by the general formula (A) ##STR1## wherein Me is a methyl group, Ph is a phenyl group, R is a methyl or phenyl group, R.sup.1 is H or a methyl group, each of m and n is 0 or more and a value of m+n is within the range of 0 to 600, a is 1, 2 or 3, b is 1, 2 or 3, c is a value of 1 to 300, and Q is a residue obtained by subtracting one isocyanate group from a compound having at least two isocyanate groups.
A process for preparing the compound having the general formula (A) comprises reacting a compound in which the moiety of --O--CO--NH--Q in the general formula (A) is not introduced yet thereinto, i.e., the moiety is --OH, with another compound having at least 2 isocyanate groups.

REFERENCES:
patent: 4387206 (1983-06-01), Bayer et al.
patent: 4644046 (1987-02-01), Yamada
Ghose, "Synthesis of Some Carbon-Functional Organosilicon Compounds", Journal of Organometallic Chemistry, 164, pp. 11-18 (1979).

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