Modified polyester useful as photographic roll film support

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528279, 528283, 528285, 528286, 528293, 528295, 528300, 528302, 528308, 5283086, 524711, 524713, 524779, 2641761, 2642107, C08G 6320

Patent

active

051380242

ABSTRACT:
A copolyester is synthesized by reacting a dialkyl ester of an aromatic dicarboxylic acid (e.g., dimethyl terephthalate) with ethylene glycol, low molecular weight poly(ethylene glycol) and a salt of a sulfonic acid-substituted aromatic dicarboxylate (e.g., sodium sulfoisophthalic acid) simultaneously in a first stage reaction in the presence of a phosphite or phosphate stabilizer. The intermediate product of the first stage is further reacted in a second stage in the presence of a polycondensation catalyst to obtain a random copolyester of the desired molecular weight. The copolyester is extruded to form a film which, after orientation and heat setting, has excellent clarity and is useful as a photographic film support. Aqueous processing of the film relaxes any core set or curl.

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Irganox 1010, Ciba-Geigy, Antitoxidant and Thermal Stabilizer, 1990.
Antioxidants Product guide, GE Specialty Chemicals, .RTM.1986.
Stabilization of Poly(Ethylene Terephthalate) with Ultranox.RTM. 626, Technical Bulletin 17A, GE Specialty Chemicals, Undated.
Weston Phosphites Product Guide, Technical Publication CA-40018, GE Specialty Chemicals, .RTM.1980.

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