Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making
Patent
1990-07-23
1991-10-22
Shine, W. J.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Silicon containing or process of making
502325, 502332, B01J 2102, B01J 2106, B01J 2362, B01J 2364
Patent
active
050595741
ABSTRACT:
The subject Fischer-Tropsch catalyst comprises moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.
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patent: 4738948 (1988-04-01), Iglesia et al.
Abrevaya, H. et al., "Metal Particle Size Effects in Fischer-Tropsch Synthesis with Supported Ruthenium Catalysts", during mtg. of Catalysis Society and reprinted in Catalysis 1987 ed, by J. W. Ward, Copyright 1988.
Lin, Zhneg-Zhong et al., "Morphology of Ru Particles on Al.sub.2 O.sub.3 and its Effect on Selectivity in Catalytic Hydrogenation of Carbon Monoxide," pp. 913-914, Chemistry Letters of the Chemical Society of Japan for 1986.
Lin, Zheng-Zhong et al., "Pronounced Effect of Particle Size on Selectivity Observed for Carbon Monoxide Hydrogenation Over Ruthenium-Alumina Catalyst," J. Chem. Soc., "Chem. Commun.", 1986 at p. 1673.
Okuhara, Toshio et al., "Effects of Additives on the Selectivity in Fischer-Tropsch Synthesis by Alumina-supported Ruthenium Catalyst", published in Chemistry Letters (9), 1491-4, 1984.
Okuhara, Toshio et al., "Effect of Potassium and Phosphorus on the Hydrogenation of CO over Alumina-Supported Ruthenium Catalyst," Journal of Catalysis, 95, 41-48 (1985).
McBride Thomas K.
Shine W. J.
Spears Jr. John F.
UOP
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