Mixed-sulfonation block copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From ketone or ketene reactant

Reexamination Certificate

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C528S373000

Reexamination Certificate

active

07598337

ABSTRACT:
Sulfonated block copolymers that may be used as membranes for fuel cells include sulfonated polyaryletherketone blocks and lightly sulfonated polyethersulfone blocks.The sulfonated polyaryletherketone blocks include structural units of formulaand the lightly sulfonated polyethersulfone blocks include structural units of formulawhereinR1, R2, R3, R4, R5and R6are independently C1-C10alkyl, C3-C12cycloalkyl, C6-C14aryl, allyl, alkenyl, alkoxy, halo, or cyano;Z, Z1and Z2are independently a direct bond or O, S, (CH2)r, (CF2)r, C(CH3)2, C(CF3)2, or a combination thereof;M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof;a and e are independently 0 or an integer from 1 to 3;b, c, d, and f are independently 0 or an integer from 1 to 4;m, n and p are independently 0 or 1; andr is an integer from 1 to 5.

REFERENCES:
patent: 2004/0186262 (2004-09-01), Maier et al.
patent: 2004/0191602 (2004-09-01), Ishikawa et al.
patent: 1113517 (2001-07-01), None
patent: 1681311 (2006-07-01), None
patent: 1449886 (2007-11-01), None
“Characterization of Polymer Blends of Polyethersulfone/Sulfonated Polysulfone and Polyethersulfone/Sulfonated Polyetheretherketone for Direct Methanol Fuel Cell Applications”, C. Manea, M. Mulder, Journal of Membrane Science 206 (2002) 443-453.
PCT International Search Report dated Oct. 19, 2007.
Roy et al., “Influence of Chemical Composition and Sequence Length on the Transport Properties of Proton Exchange Membranes”, Journal of Polymer Science, Polymer Physics, vol. 44, pp. 2226-2239, 2006.

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