Mixed conductors of graphite, processes for their preparation an

Details Mixed conductors of graphite, processes for their preparation an Mixed conductors of graphite, processes for their preparation an

1973-08-17

1976-05-11

Sebastian, Leland A.

Compositions

Electrically conductive or emissive compositions

Elemental carbon containing

252506, 260429R, 2604381, 2604385R, 260439R, 136120R, 136121, H01B 106

Patent

active

039561941

ABSTRACT:
New mixed conductors resulting from the insertion of an alkali element in the lattice of an intercalation compound of graphite and of a product M'.sub.y X.sub.z : M' is a transition metal such as Ti, V, Cr, Mn, Fe, Mo; X is a nonmetallic electronegative atom such as O, S, F, Cl or Br; y and z have the values of the indices in said product M'.sub.y X.sub.z. These mixed compounds are useful for the manufacture of positive electrodes of electrochemical generators.

REFERENCES:
patent: 3409563 (1968-11-01), Olstowski
patent: 3759842 (1973-09-01), Bianchi et al.
Journal of American Chemical Society, Vol. 78 (1956), "Reactions of Sodium Metal with Aromatic Hydrocarbons," pp. 116-120.
R. C. Croft, "New Molecular Compounds of Graphite," (Third Biennial Carbon Conference), 1958, pp. 315-319.
Quarterly Reviews-Croft: "Lamellar Compounds of Graphite," Proceedings of London Chemical Society (Chemical Soc. London), Vol. 14, pp. 1-45 (1960).
M. E. Vol'Pin et al.-Izvestiya Akademii Nauk USSR, Seriya Khimicheskaya, No. 11, pp. 2608-2609 (Nov. 1970).
M. B. Armand-"Fast Publisher, Transport in Solids," Van Gool (Editor), North Holland Publisher, (1972).
"L.' Insertion Dans Les Carbones," (Les Carbones, Groupe Francais des Carbones), Masson (Ed.), Paris (1955), pp. 564, 582.

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