Compositions: ceramic – Ceramic compositions – Titanate – zirconate – stannate – niobate – or tantalate or...
Reexamination Certificate
2002-10-21
2004-08-17
Group, Karl (Department: 1755)
Compositions: ceramic
Ceramic compositions
Titanate, zirconate, stannate, niobate, or tantalate or...
Reexamination Certificate
active
06777362
ABSTRACT:
TECHNICAL FIELD
The present invention relates to a microwave dielectric ceramic composition employed in resonator materials or capacitor materials etc used in the microwave region of a few GHz.
BACKGROUND ART
Dielectrics are used in the resonators, filters, or capacitors that are used in transceivers for for example satellite communication broadcasting or mobile identification devices using microwaves of a few GHz.
As such dielectric ceramic materials, for example BaO—TiO
2
—Nd
2
O
3
—Bi
2
O
3
compositions have been proposed (Laid-open Japanese Patent Application No. Sho. 61-8806). The dielectric constant ∈ of this composition is of the order or 70 to 110; when dielectric resonators or capacitors are constructed, materials of larger dielectric constant ∈ are preferred since the larger the dielectric constant ∈ of the material that is used, the smaller are the dimensions of the resonator.
Conventional materials of large dielectric constant ∈ include for example SrTiO
3
and CaTiO
3
etc; while their dielectric constant ∈ is very large at 300 and 180, the temperature coefficient &tgr;f of the resonance frequency is extremely large at +1700 ppm/°C. and +800 ppm/°C., which means that it is not possible to use them.
Accordingly, as a method of lowering the temperature coefficient &tgr;f of a dielectric ceramic composition, the method is available of preparing a material whose dielectric constant ∈ is as large as possible and whose temperature coefficient &tgr;f has a negative value; with this method, a ceramic composition can be obtained by a suitable composition whose dielectric constant ∈ is large and whose temperature coefficient &tgr;f of resonance frequency is small.
For example, Laid-open Japanese Patent Publication No. H. 5-211009 proposes the obtaining of a ceramic composition of large dielectric constant ∈ and whose temperature coefficient of resonance frequency &tgr;f is close to zero, by preparing a material represented by the compositional formula (A
1+
1/2
.B
3+
1/2
) TiO
3
where A
1+
is Li
1+
, and B
3+
is Nd
3+
, Sm
3+
, Co
3+
or Pr
3+
, constituting a material of large dielectric constant ∈ and wherein the temperature coefficient &tgr;f has a negative value.
However, the demands for miniaturization of portable electronic terminal equipment have today become so exacting that a material having even higher dielectric constant ∈ is earnestly sought for the dielectric material of resonators, filters and capacitors employed in such devices.
DISCLOSURE OF THE INVENTION
In view of the characteristics required for a dielectric ceramic composition for microwaves, an object of the present invention is to obtain a dielectric ceramic composition wherein the dielectric constant ∈ is large, the temperature coefficient &tgr;f of the resonance frequency is close to 0, and which has a large Q value, by adding to and blending with a ceramic composition whose &tgr;f of the resonance frequency is large on the plus side to a ceramic composition whose temperature coefficient &tgr;f is large on the minus side.
With the object of providing a dielectric ceramic composition whose dielectric constant ∈ is large, whose temperature coefficient of resonance frequency &tgr;f is close to 0, and whose Q value is large, the present inventors have previously proposed a dielectric ceramic composition represented by the compositional formula Li
2
O—Na
2
O—Bi
2
O
3
—R
2
O
3
—TiO
2
, where R
2
O
3
is one or two or more of La
2
O
3
, Nd
2
O
3
, Sm
2
O
3
, Co
2
O
3
or Pr
2
O
3
(Japanese Patent Application Number 2000-337141).
Also, the present inventors have proposed (Japanese Patent Application Number 2000-340104) a dielectric ceramic composition represented by the compositional formula Li
2
O—Bi
2
O
3
—R
2
O
3
—SrTiO
3
, where R
2
O
3
is one or two or more of La
2
O
3
, Nd
2
O
3
, Sm
2
O
3
, Co
2
O
3
or Pr
2
O
3
.
As a result of further assiduous investigation, the present inventors discovered that an excellent dielectric characteristic could be obtained in stable fashion by co-presence of specific quantities of Bi
2
O
3
, Na
2
O and MO (where M is one or two of Ca and Sr) in the one or two or more of La, Nd, Pr and Sm constituting R, in the Li
2
O—R
2
O
3
—TiO
2
-based composition.
Specifically, the present inventors discovered that, in an Li
2
O—R
2
O
3
—TiO
2
-based composition, an improved dielectric constant ∈ could be achieved by introducing a specific quantity of Bi
2
O
3
, and &tgr;f could be shifted to the plus side and in addition the effect of a considerable improvement in Qf achieved by introducing a specific quantity of MO (where M is one or two of Ca and Sr).
They discovered that, by introducing MO, &tgr;f becomes too large, making it difficult to make &tgr;f approach 0 while maintaining Qf at a fixed value, so, by introducing a specific quantity of Na
2
O together with the MO (where M is one or two of Ca and Sr), in particular in the case of material of ∈r>150, it was possible to control &tgr;f to the vicinity of 0 while maintaining Qf at an high value, and thereby perfected the present invention.
Specifically, the present invention consists in a microwave dielectric ceramic composition represented by the compositional formula
a
Li
2
O-
b
Na
2
O-
c
R
2
O
3
-
d
Bi
2
O
3
-
e
MO-
f
TiO
2
(where a+b+c+d+e+f=100, a, b, c, d, e and f being mol %) where R includes one or two or more of Nd, Sm, Pr, and La, M includes one or two of Ca and Sr and a, b, c, d, e, f satisfy 5<a<15, 0<b<10, 3<c<15, 1<d<15, 1<e<30, and 40<f<75.
BEST MODE FOR CARRYING OUT THE INVENTION
In the present invention, in the Li
2
O—Na
2
O—R
2
O
3
—Bi
2
O
3
—MO—TiO
2
-based composition (where R is one or two or more of Nd, Sm, Pr, and La and M is one or two of Ca and Sr), if Li
2
O is less than 5 mol %, the dielectric constant is low and &tgr;f becomes too large on the plus side; while if it exceeds 15 mol %, Li
2
O being of low melting-point, this is undesirable because there is the problem that the ceramic composition reacts and fuses with the base plate or base powder during sintering. A range of 5<a<15 mol % is therefore specified for Li
2
O (a).
Also, if Na
2
O exceeds 10 mol %, this is undesirable because it gives rise to the problem that &tgr;f becomes too large on the plus side, and Qf falls. Accordingly, a range of 0<b<10 mol % is specified for Na
2
O (b).
If R
2
O
3
(R
3+
is one or two or more of Nd
3+
, Sm
3+
, Pr
3+
, and La
3+
) is less than 3 mol %, the dielectric constant is low and Q is also poor; if it exceeds 15 mol %, there is little benefit and costs are increased, which is undesirable. A range of 3<c<15 mol % is therefore specified for R
2
O
3
(c).
Bi
2
O
3
has the effect of increasing the dielectric constant ∈ and a content thereof of at least 1 mol % is necessary; however, because of its lower melting-point, if it exceeds 15 mol %, there is a risk that the ceramic composition will react and fuse with the base plate or base powder on sintering; this is therefore undesirable. Accordingly, a range of 1<d<15 mol % is specified for Bi
2
O
3
(d).
Also, the content of MO (where M is one or two of Ca and Sr) has the benefit of improving Qf and improving the temperature coefficient &tgr;f; however, if it is less than 1 mol %, there is little benefit in terms of improving Qf and improving the temperature coefficient &tgr;f and if it exceeds 30 mol %, the temperature coefficient &tgr;f becomes too large on the plus side, which is undesirable. Accordingly, a range of 1<e<30 mol % is specified for MO (e).
In addition, if TiO
2
is less than 40 mol %, the required crystalline phase is not obtained and the required dielectric characteristic is not obtained; if it is more than 75 mol %, the problem arises that a phase consisting of TiO
2
on its own appears, severely lowering Qf, which is undesirable. A range of 40<f<75 mol % is therefore specified fo
Fukagawa Tomoki
Nishikawa Kazuhiro
Dykema Gossett PLLC
Group Karl
Sumitomo Special Metals Co. Ltd.
LandOfFree
Microwave dielectric ceramic composition does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Microwave dielectric ceramic composition, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Microwave dielectric ceramic composition will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3342525