Microporous square pyramidal-tetrahedral framework vanadium phos

Details Microporous square pyramidal-tetrahedral framework vanadium phos Microporous square pyramidal-tetrahedral framework vanadium phos

1995-11-29

1997-02-11

Nazario-Gonzalez, Porfirio

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 17, 556 26, 556 42, C07F 902

Patent

active

056022662

ABSTRACT:
A new class of vanadium phosphate materials using a mixed valence pentavanadate as the building block has been created using hydrothermal self-assembly techniques. These materials use a framework composed solely of V.sub.5 O.sub.9 (PO.sub.4).sub.4/2 pentamers and apart from the cationic template contain some of the largest voids and cavities yet reported in open framework solids.

REFERENCES:
patent: 4956483 (1990-09-01), Corcoran, Jr. et al.
patent: 5200187 (1993-04-01), Haushalter et al.
patent: 5324848 (1994-06-01), Haushalter et al.

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