Microcapsules containing oils and soluble color reaction compone

Record receiver having plural interactive leaves or a colorless – Having a colorless color-former – developer therefor – or... – Method of use – kit – or combined with marking instrument or...

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264 47, 42840221, 428914, 503214, 503215, B01J 1302, B41M 516, B41M 522

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active

048248231

ABSTRACT:
A process for microencapsulating hydrophobic oils with color reactants, dissolved therein, of color reaction systems by reacting a water-soluble non-ionic melamine/formaldehyde precondensate and a water-soluble polymer in an oil-in-water dispersion for forming the capsule envelope is described. The special feature of this process is that, for stabilizing the oil-in-water dispersion, an aqueous solution of a cationic melamine/formaldehyde precondensate and the aqueous solution of a water-soluble polymer are mixed with vigorous stirring, a solid precipitating as a very fine suspension in the mixture, the mixture thus obtained and containing the very finely suspended solid is mixed with ther oil, containing the color reactant in solution, with vigorous stirring, the oil-in-water dispersion thus obtained in acidified and an aqueous solution of a water-soluble non-ionic melamine/formaldehyde precondensate is added with stirring, in order to form the capsule envelope. The use of the cationic melamine/formaldehyde precondensate leads to the precipitation of a very finely suspended reaction product thereof, whereby all the reaction systems in the course of the process are stabilized. Excellent capsules can be obtained without formation of agglomerates. The invention also relates to the microcapsules obtainable by the above process and to their advantageous use in color reaction recording systems.

REFERENCES:
patent: 4369670 (1983-08-01), Sinclair
patent: 4525520 (1985-06-01), Shioi et al.
"Flow Measurement", Kirk-Other Concise Encyclopedia of Chemical Technology, 1985, p. 496.

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