Microarrays having multiple oligonucleotides in single array...

Chemistry: molecular biology and microbiology – Measuring or testing process involving enzymes or... – Involving nucleic acid

Reexamination Certificate

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C435S287200, C536S023100, C536S025300, C536S025310

Reexamination Certificate

active

07846660

ABSTRACT:
The present invention is a method for synthesizing microarrays having different oligonucleotides present within one feature area of the array. The method utilizes the techniques common to microarray synthesis, but limits the duration in which selected feature areas on the array are initially dosed with light so as to only deprotect a calculated ratio of the compounds forming the array's binding layer. The compounds initially deprotected are capped with a non-photosensitive protecting group, such as di-methoxy-trityl, to inhibit their involvement in the synthesis of a first group of DNA strands built onto the array. Once the first group of DNA strands have been synthesized, the original deprotected group may then be further processed to build one or more groups of DNA strands in the same feature area as the first group of DNA strands. The present invention also includes microarrays manufactured using the method.

REFERENCES:
patent: 5959098 (1999-09-01), Goldberg et al.
patent: 6426184 (2002-07-01), Gao et al.
patent: WO 9509248 (1995-04-01), None
patent: WO00/11223 (2000-03-01), None
Beier et al, Synthesis of photolabile 5′-O-phosparamidites for photolithographic production of microarrays of inversely oriented oligonucleotides, 2001, Helvetic Chimica Acta, 84, 2089-2095.
Albert et al., “Light-directed 5′—3′ synthesis of complex oligonucleotide microarray.” Nucleic Acids Research, 31:e35, 2003.

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