Methylene and oxymethylene bis-ester production

Details Methylene and oxymethylene bis-ester production Methylene and oxymethylene bis-ester production

1989-10-27

1991-04-16

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid anhydrides

C07C 5156

Patent

active

050084518

ABSTRACT:
Methylene and oxymethylene bis-esters are produced by the reaction of an aliphatic ester of a carboxylic acid, formaldehyde and carbon monoxide in the presence of a catalytic amount of a Group VIII noble transition metal compound, an iodide or bromide promoter, and a proton donor.

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Falbe, CO in Organic Synthesis, 1970, pp. 113-117.

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