Methyl 3-azido-4-C-cyano-2,3,4,6-tetradeoxy-.alpha.-D-arabino-he

Details Methyl 3-azido-4-C-cyano-2,3,4,6-tetradeoxy-.alpha.-D-arabino-he Methyl 3-azido-4-C-cyano-2,3,4,6-tetradeoxy-.alpha.-D-arabino-he

1981-03-30

1982-09-07

Chan, Nicky

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

2602452T, C07D30914

Patent

active

043483259

ABSTRACT:
Disclosed is methyl 3-azido-4-C-cyano-2,3,4,6-tetradeoxy-.alpha.-D-arabino-hexopyranoside and processes for its preparation from methyl 3-azido-2,3,6-trideoxy-.alpha.-D-arabino-hexopyranoside via the 4-bromo-4-deoxy intermediate; wherein the two inversions of configuration at C-4 result in a net retention of the .alpha.-D-arabino stereochemistry.

REFERENCES:
patent: 4234596 (1980-11-01), Christensen et al.

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