Methods of preparing pentanitrotoluene

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 7910

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044516819

ABSTRACT:
Pentanitrotoluene is prepared by a method which comprises preparing an amdinitrotoluene from a precursor of either TNT or 2,5-dinitro-3-methylbenzoic acid, nitrating the aminodinitrotoluene to produce a nitramine intermediate, converting the nitramine intermediate to an aminotetranitrotoluene and oxidizing the aminotetranitrotoluene with peroxydisulfuric acid to pentanitrotoluene. Pentanitrotoluene is an explosive.

REFERENCES:
patent: 2036530 (1936-04-01), Knecht et al.
patent: 3087972 (1963-04-01), Emmons et al.
patent: 3507924 (1970-04-01), Hakansson et al.
patent: 4262148 (1981-04-01), Nielsen et al.
Nielsen et al., J. Org. Chem., 45, 2341 (1980).

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