Methods of photocatalytic decarboxylation of saturated carboxyli

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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C07C 324

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043034861

ABSTRACT:
Methods for heterogeneous photocatalytic decarboxylation of saturated carboxylic acids on several n-type semiconductor powders are disclosed. Major reaction products are the corresponding alkanes and carbon dioxide.

REFERENCES:
patent: 2940913 (1960-06-01), McKusick
patent: 2940914 (1960-06-01), Hoover
Frank et al., J. Am. Chem. Soc., vol. 99, pp. 303 and 304 (1977).
Frank et al., Journal of Physical Chemistry, vol. 81, No. 15, pp. 1484-1488 (1977).
Kraeutler et al. (1), J. Am. Chem. Soc., vol. 99, pp. 7729-7731 (1977).
Kraeutler et al. (2), J. Am. Chem. Soc., vol. 100, pp. 4903-4905, (Jul. 5, 1978).

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