Wells – Processes – Producing foam or gas in well by foaming or gas producing...
Reexamination Certificate
2002-05-31
2004-04-06
Bagnell, David (Department: 3677)
Wells
Processes
Producing foam or gas in well by foaming or gas producing...
C166S300000, C166S305100, C166S312000, C175S069000, C175S072000, C507S102000, C106S677000, C106S672000
Reexamination Certificate
active
06715553
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to methods of chemically generating gas in aqueous fluids utilized in the drilling and completion of wells such as drilling fluids, spacer fluids and aqueous acid solutions.
2. Description of the Prior Art
Foamed aqueous fluids have heretofore been utilized in a number of oil and gas well applications. Typically, the aqueous fluids are foamed by combining mixtures of foaming and foam stabilizing surfactants with the fluids on the surface followed by injecting gas, typically nitrogen, into the fluids containing the foaming and foam stabilizing surfactants as the fluids are pumped to the well head and into the well bore. This process allows the final foamed fluid to have gas concentrations of 1% to 80% by volume of the fluid depending on the downhole pressure and temperature and the amount of gas injected at surface. The equipment and personnel required for storing the nitrogen in liquid or gaseous form and injecting it into well fluids is very elaborate and expensive. In addition, the equipment is frequently unavailable or cannot be easily transported to well sites due to their remote locations.
In-situ gas forming agents have been utilized heretofore in well cement compositions to prevent annular gas migration. For example, surfactant coated finely ground aluminum has been included in cement compositions to generate hydrogen gas in the compositions as they are being pumped down a well bore and after they are placed in the annulus between the walls of the well bore and casing or other pipe string therein. The presence of the gas in the cement compositions prevents formation fluids from entering the cement compositions as the cement compositions develop gel strength. That is, the development of gel strength and the cement hydration reaction that takes place reduces the ability of a cement composition column to transmit hydrostatic pressure. If the hydrostatic pressure of the cement composition column falls below the formation pore pressure before the cement composition has gained sufficient strength to prevent the entry of formation fluids into the well bore, the fluids enter the well bore and form channels in the cement composition column which remain after the cement composition column sets. The presence of the gas which is generated in the cement composition from the finely ground aluminum increases the volume of the cement composition such that the volume increase generated by the gas equals or slightly exceeds the cement composition volume reduction during the development of gel strength due to fluid loss and/or the cement hydration reaction. The increase in volume, typically less than 5%, and the compressibility produced in the cement composition by the gas allows the cement composition column to resist the entry of formation fluids into the well bore.
Other gas forming agents have also been added to well cement compositions to gasify the compositions. For example, U.S. Pat. No. 4,450,010 issued on May 22, 1984 to Burkhalter et al. discloses a well cementing method and gasified cements useful in carrying out the method. That is, U.S. Pat. No. 4,450,010 discloses a method of cementing in subterranean formations using a gasified cement composition which prevents formation fluids from entering the cement composition column formed in the annulus between the well bore and a pipe string therein. The cement composition includes a nitrogen gas generating material, an oxidizing agent and a reaction rate control material whereby a quantity of gas is generated in the cement composition to offset the shrinkage in the cement composition column as it develops gel strength and to provide compressibility thereto whereby the entry of formation fluids into the well bore is reduced or prevented.
A situation where the presence of gas would provide a distinct advantage involves problems associated with high fluid pressure buildup behind casing. Occasionally, aqueous drilling fluids, spacer fluids or both are left behind casing during the cementing phase of well construction. When the well is put on production, the formation temperature heats up the trapped drilling and/or spacer fluids causing severe high pressure buildups due to the incompressibility of the fluids which can cause damage to the casing. The presence of a compressible gas behind the casing in drilling fluids, spacer fluids and the like, either in the form of a gas pocket or foam would help sustain the temperature increases without severe pressure buildups.
Other applications where the presence of gas in aqueous drilling fluids, aqueous spacer fluids, aqueous acid solutions and the like would provide distinct advantages include drilling and well treating fluid hydrostatic pressure reduction to prevent formation fractures, drill cuttings removal, the displacement of drilling fluids in an eccentric annulus, hydrostatic fracture pressure control, fluid loss control and spent acid solution recovery.
While the methods of the prior art have achieved varying degrees of commercial success, there is a need for improved methods of generating gas in and foaming well fluids whereby elaborate and expensive equipment for producing the gas is not required.
SUMMARY OF THE INVENTION
The present invention provides improved methods of generating gas in and foaming well fluids such as aqueous drilling fluids, aqueous spacer fluids, aqueous acid solutions and the like introduced into subterranean zones penetrated by well bores which meet the needs described above and overcome the deficiencies of the prior art. In accordance with this invention nitrogen gas is generated chemically in aqueous drilling fluids, spacer fluids and the like in a concentration of from about 1% to about 80% of the fluid volume for the purpose of preventing trapped fluid pressure increases, reducing fluid hydrostatic pressure, removing drill cuttings, displacing drilling fluids in an eccentric annulus, controlling fracture pressure and controlling fluid loss.
An improved method of the present invention for generating gas in and foaming an aqueous drilling fluid, an aqueous spacer fluid and other similar well fluids comprises the following steps. One or more gas generating chemicals are combined with the aqueous well fluid on the surface. At approximately the same time, a mixture of foaming and foam stabilizing surfactants and when needed, an activator for said one or more gas generating chemicals selected from a base or buffer for increasing the pH of the well fluid to in the alkaline range of from about 10 to about 14 or one or more oxidizing chemicals are combined with the well fluid so that the gas generating chemical or chemicals react with the alkaline well fluid or the oxidizing chemical or chemicals and gas and foam are formed in the fluid while it is being pumped. Thereafter, the well fluid containing the gas generating chemicals, the foaming and foam stabilizing surfactants and when needed, an activator is pumped into a well bore.
Gas generating chemicals which are useful in accordance with the present invention include, but are not limited to, compounds containing hydrazine or azo groups, for example, hydrazine and its salts with acids, azodicarbonamide, azobis(isobutyronitrile), p-toluene sulfonyl hydrazide, p-toluene sulfonyl semicarbazide, carbohydrazide, p-p′-oxybis(benzenesulfonylhydrazide and mixtures thereof. Additional examples of nitrogen gas generating chemicals which do not contain hydrazine or azo groups which are also useful in the present invention include, but are not limited to, ammonium salts of organic or inorganic acids, hydroxylamine sulfate, carbamide and mixtures thereof.
An improved method of chemically generating gas in and foaming an aqueous acid solution introduced into a subterranean zone penetrated by a well bore to increase the hydrocarbon permeability of the zone or other similar purpose is also provided by the present invention. The presence of the gas in the acid solution assists the recovery of the spent acid from the subterranean zone. The meth
Cox Ricky A.
Dennis, Jr. John L.
Griffith James E.
Luke Karen
Ravi Krishna M.
Bagnell David
Bomar T. Shane
Dougherty, Jr. C. Clark
Roddy Craig W.
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