Methods of controlling molecular weight distribution of...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

Reexamination Certificate

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C502S102000, C502S103000, C502S117000, C502S161000, C502S155000, C502S160000, C526S126000, C526S127000, C526S160000, C526S161000, C528S196000, C528S198000

Reexamination Certificate

active

07858729

ABSTRACT:
A catalyst, co-catalyst, and/or chain transfer agent is added at a time after initiation of an addition polymerization reaction to produce a polymer product with a widened molecular weight distribution relative to having all of the components in the original reaction mixture. The catalyst, co-catalyst, or chain transfer agent may be added discretely or continuously to the reaction to produce a product with a bimodal, trimodal, or other broadened molecular weight distribution.

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patent: 2009130182 (2009-10-01), None
Coates and Moore, Discrete Metal-Based Catalysts for Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism, Angew. Chem., Int. Ed., 2004, vol. 43, pp. 6618-6639.
Qin et al., Cobalt-Based Complexes for the Copolymerization of Propylene Oxide and CO2: Active and Selective Catalysts for Polycarbonate Synthesis, Angew. Chem., Int. Ed., 2003, vol. 42, pp. 5484-5487.
Cohen et al., Cobalt Catylysts for the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide: Combing High Activity and Selectivity, J. Am. Chem. Soc., 2005, vol. 127, pp. 10869-10878.
International Search Report and Written Opinion for PCT/US2009/045216, Jan. 11, 2010, 11 pages.

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