Methods of, and apparatus for, proton decoupling in nuclear magn

Electricity: measuring and testing – Particle precession resonance – Using a nuclear resonance spectrometer system

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G01R 3308

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046821066

ABSTRACT:
A method for proton decoupling, nuclear Overhauser enhancement and/or in selective saturation magnetic resonance spectroscopy, particularly relevant to in vivo spectroscopic imaging, utilizes a radio-frequency pulse modulated with a truncated (sinc X)/X function capable of being windowed. The radio-frequency pulse is tuned to the frequency of the nuclear species, such as .sup.1 H, to be decoupled or saturated and has a bandwidth adjusted to correspond to the entire chemical shift spectrum of the nuclear species to be decoupled, minimizing the amount of radio-frequency power transmitted into a volume of the irradiated sample. Several methods, and several embodiments of apparatus, for forming the required radio-frequency pulse, are disclosed.

REFERENCES:
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"Coherent Broad-Band Decoupling-An Alternative to Proton Noise Decoupling in Carbon-13 Nuclear Magnetic Resonance Spectroscopy", Grutzner et al., J. Magn. Reson. 19, pp. 173-187 (1975).
"Composite Pulse Decoupling", Levitt et al., J. Magn. Reson. 43, pp. 502-507 (1981).
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"Utilization of Chirp Frequency Modulation with 180.degree.-Phase Modulation for Heteronuclear Spin Decoupling", Basus et al., J. Mag. Reson., 35, pp. 19-37 (1979).
"Theory of Broadband Spin Decoupling", J. S. Waugh, J. Mag. Reson., 50, pp. 30-49 (1982).

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