Methods of activating chromium catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C502S020000, C502S034000, C502S035000, C502S049000

Reexamination Certificate

active

07981832

ABSTRACT:
New methods for activating chromium catalysts for polymerization processes decrease the amount of time required for activation and increase catalyst activity. Rapid heating to a first temperature is followed by a first hold period before heating to a higher second temperature and maintaining the second temperature for a second hold period. In one aspect, the overall activation process takes less than 10 hours.

REFERENCES:
patent: 2951816 (1960-09-01), Hogan et al.
patent: 3248179 (1966-04-01), Norwood
patent: 3281405 (1966-10-01), Hogan
patent: 3362946 (1968-01-01), Hogan
patent: 3446754 (1969-05-01), Solvik et al.
patent: 3624063 (1971-11-01), Witt
patent: 4022580 (1977-05-01), Rush
patent: 4041224 (1977-08-01), Hoff et al.
patent: 4136061 (1979-01-01), Hogan et al.
patent: 4151122 (1979-04-01), McDaniel et al.
patent: 4247421 (1981-01-01), McDaniel et al.
patent: 4296001 (1981-10-01), Hawley
patent: 4397769 (1983-08-01), McDaniel et al.
patent: 4424341 (1984-01-01), Hanson et al.
patent: 4501885 (1985-02-01), Sherk et al.
patent: 4613484 (1986-09-01), Ayres et al.
patent: 4737280 (1988-04-01), Hanson
patent: 5006506 (1991-04-01), Hsieh et al.
patent: 5200478 (1993-04-01), Vogels et al.
patent: 5565175 (1996-10-01), Hottovy et al.
patent: 5597892 (1997-01-01), Hanson
patent: 6239235 (2001-05-01), Hottovy et al.
patent: 6359085 (2002-03-01), Lhost et al.
patent: 6617404 (2003-09-01), Shveima
patent: 7223823 (2007-05-01), Lin
patent: 7271122 (2007-09-01), Bodart et al.
patent: 7384885 (2008-06-01), Roger et al.
patent: 7615510 (2009-11-01), McDaniel et al.
patent: 2005/0192177 (2005-09-01), Roger et al.
patent: 0857737 (1998-08-01), None
patent: 0882740 (1998-12-01), None
patent: 2005113146 (2005-12-01), None
Bird, R. Byron, et al., “Dynamics of Polymeric Liquids,” vol. 1, Fluid Mechanics, Second Edition, 1987, Cover and publishing info (2 pages), xiii-xviii, and pp. 171-172, Wiley-Interscience Publications, John Wiley & Sons.
Foreign communication from a related counterpart application—International Preliminary Report on Patentability, PCT/US2005/016108, 9 pages, Nov. 14, 2006.
Foreign communication from a related counterpart application—International Search Report and Written Opinion, PCT/US2005/016108, 12 pages, Sep. 27, 2005.
Hieber, C.A., et al., “Shear-rate-dependence modeling of polymer melt viscosity,” Polymer Engineering and Science, Jul. 1992, vol. 32, No. 14, pp. 931-938.
Hieber, C.A., et al., “Some correlations involving the shear viscosity of polystyrene melts,” Rheologica Acta, 1989, vol. 28, pp. 321-332.
McDaniel, M.P., et al., “The Activation of the Phillips Polymerization Catalyst,” Journal of Catalysis, 1983, vol. 82, pp. 118-126.
McDaniel, M.P., “The State of Cr(VI) on the Phillips Polymerization Catalyst, IV. Saturation Coverage,” Journal of Catalysis, 1982, vol. 76, pp. 37-47, Academic Press.
McDaniel, Max P., “Excess Oxygen of Chromia, I,” Journal of Catalysis, 1975, vol. 36, pp. 394-403, Academic Press.
McDaniel, Max P., “Excess Oxygen of Chromia, II. Reaction with Dephenylpicrylhydrazine,” Journal of Catalysis, 1975, vol. 36, pp. 404-412, Academic Press.
Welch, M. B., et al., “The Activation of the Phillips Polymerization Catalyst, II. Activation by Reduction/Reoxidation,” Journal of Catalysis, 1983, vol. 82, pp. 110-117, Academic Press.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Methods of activating chromium catalysts does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Methods of activating chromium catalysts, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Methods of activating chromium catalysts will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2736343

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.