Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Reexamination Certificate
2011-07-12
2011-07-12
Shameem, Golam M (Department: 1626)
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
C546S013000, C544S106000
Reexamination Certificate
active
07977508
ABSTRACT:
Methods of synthesizing ammonia borane are provided. The methods comprise reacting at least one amine borane with ammonia such that ammonia borane is produced. Ammonia borane has a chemical formula Of NH3—BH3and provides a good source of storage hydrogen making it useful in a variety of applications including a potential hydrogen source for fuel cells. The methods can further comprise separating the ammonia borane from the other products of the reaction. Exemplary methods can produce ammonia borane having purity greater than about 90 percent. In further examples, the methods can produce ammonia borane having purity greater than about 95 percent or greater than about 99 percent.
REFERENCES:
patent: 4157927 (1979-06-01), Chew et al.
patent: 2007/120511 (2007-10-01), None
International Search Report from PCT/US07/08160 dated Jul. 7, 2008.
Beres et al., “Dimethyl Sulfide-Burane as a Borane Carrier”, Inorganic Chemistry, vol. 10, No. 9, pp. 2072-2074, 1971.
Brown et al., “Molecular addition compounds. 9. Effect of structure on the reactivities of representative borane-amine complexes in typical reactions such as hydrolysis, hydroboration, and reduction”, Inorg. Chem, 1984, 23, 2746-2753.
Brown et al., “Molecular addition compounds. 10. Borane adducts with N,N-Dialkylanilines for hydroboration”, Organometallics, 17, pp. 4202-4205, 1998.
Fakioglu et al., “A review of hydrogen storage systems based on boron and its compounds”, Int J of Hydrogen Energy, vol. 29, issue 13, Oct. 2004, pp. 1371-1376.
Hu et al., “New synthetic approaches to ammonia-borane and its deuterated derivatives”, J Inorg Nucl Chem, vol. 39, pp. 2147-2150, vol. 39, 1977, printed Great Britain.
Jaska et al., “Transition Metal-catalyzed formation of boron-nitrogen bonds: catalytic dehydrocoupling of amine-borane adducts to form aminoboranes and borazines”, J Am Chem Soc, 125, 9424-9434, 2003.
Mayer, Erwin “Symmetrical cleavage of diborane by ammonia in solutioin”, Inorganic Chemistry, vol. 11, No. 4, 1972, pp. 866-869.
Narayana et al., “A simple convenience method for the generation of diborane from NaBH4 and I2”, J of Organometallic Chemistry, 323, pp. 145-157, 1987, printed in the Netherlands.
T-Raissi, “Technoeconomic analysis of area II hydrogen production—part II Hydrogen from Ammonia and Ammonia-borane complex for fuel cell applications”, Proceedings of the 2002, U.S. DOE Hydrogen Program Review, NREL/CP-610-32405, pp. 1-17.
T-Raissi, “V.A. System Analysis. V.A.1 Analysis of hydrogen production using ammonia and ammonia-borane complex for fuel cell applications”, Hydrogen, Fuel Cells, and Infrastructure Technologies, FY 2002 Progress Report, pp. 537-542.
Reetz, Theodor “Hexaalkyl phosphorous triamide borines”, vol. 82, pp. 5036-5039, J Am Chem Society, 1960.
Shore et al., “The crystalline, compound ammonia-borane, H3NBH2”, Communications to the Editor, vol. 77, pp. 6084-6085, Nov. 20, 1955.
Shore et al., “Large Scale Synthesis of H2B(NH3)2+BH2-and H3NBH3”, Inorganic Chemistry, vol. 3, No. 6, pp. 914-915, 1964.
Shore et al., “Diamminedihydroboron (1+) tetrahydroborate (Diammoniate of Diborane)”, Inorganic Syntheses, vol. 9, copyright 1967, pp. 4-8.
Solomons, T.W., “Organic Chemistry”, third edition, John Wiley & Sons, copyright 1984, printed U.S., cover pages, pp. 834-841 and 878-879.
Chen Xuenian
Shore Sheldon Gerald
Calfee Halter & Griswold LLP
Shameem Golam M
The Ohio State University
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