Methods for reversibly storing hydrogen

Chemistry of inorganic compounds – Hydrogen or compound thereof – Elemental hydrogen

Reexamination Certificate

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Details

C423S286000, C423S644000, C423S645000, C423S646000, C423S647000

Reexamination Certificate

active

07462344

ABSTRACT:
The invention provides a method of reversibly storing hydrogen at industrially practicable temperature and pressure conditions. A stable hydrogen storage hydride is mixed with a destabilizing hydride. The stable hydride is capable of releasing hydrogen at a first energy level. When the stable hydride is in the presence of the destabilizing hydride, the stable hydride releases hydrogen at a second energy level. The second energy level is significantly reduced from the first energy level.

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Vajo et al, “Reversible Storage of Hydrogen in Destabilized LiBH4”, J. Phys. Chem. B, 109(9) pp. 3719-3722 (published on the web on Feb. 12, 2005).
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Alapati et al “Identification of Destabilized Metal Hydrides for Hydrogen Storage Using First Principles Calculations”, J. Phys. Chem. B110, 8769-8776 (2006), no month.
Johnson, Session D6: Simulating Hydrogen Storage: From Current Challenges to Future Promises, 2006 APS March Meeting Event, Abstract D6.00001, no month.
Vajo et al, Altering Hydrogen Storage Properties by Hydride Destabilization through Alloy Formation, J. Phys. Chem. B, 108 (37) pp. 13977-13983 (2004).
Johnson et al, “Computational Studies of Hydrogen Storage: Metal Organic Frameworks and Destabilized Metal Hydrides”, found on the web at www.h-workshop.uni-konstanz.de/talks.
Alapati et al “Identification of Destabilized Metal Hydrides for Hydrogen Storage Using First Principles Calculations”, J. Phys. Chem. B110, 8769-8776 (2006).
Johnson, Session D6: Simulating Hydrogen Storage: From Current Challenges to Future Promises, 2006 APS March Meeting Event, Abstract D6.00001.

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