Methods for recycling electric arc furnace dust

Specialized metallurgical processes – compositions for use therei – Processes – Electrothermic processes

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75 1022, 75420, 423108, C21B 1110, C22B 702

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055385320

ABSTRACT:
A method for the separation and recovery of metals selected from the group consisting of iron, cadmium, zinc, and lead, from raw material comprising a mixture of metals, which comprises the steps of heating the raw material to a temperature sufficient to substantially vaporize cadmium, zinc, and lead, and insufficient to substantially vaporize iron; separating secondary dust and vapors produced during the first step from the residual sinter mass, which mass comprises iron; slurrying the secondary dust in an aqueous solution of ammonia ammonium carbonate to dissolve zinc and cadmium; separating a zinc/cadmium bearing leach liquor from substantially insoluble lead containing particles by filtration; treating the zinc/cadmium bearing leach liquor to recover cadmium by adding metallic zinc to the leachate to produce a cadmium containing cement; separating the cement from the leach liquor; and removing ammonia from the leach liquor to precipitate basic zinc carbonate. The methods of the invention are especially suitable for treating electric arc furnace dusts.

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