Methods for recycling catalyst compositions for aromatic...

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Gas or vapor treating

Reexamination Certificate

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Details

C502S029000, C502S161000, C502S168000, C570S208000, C570S209000, C570S210000, C423S046000, C423S493000

Reexamination Certificate

active

07863209

ABSTRACT:
A method for recovering and reusing a ring-halogenation catalyst comprises: (A) contacting an aromatic compound with chlorine or bromine in the presence of a catalyst composition, where the catalyst composition comprises at least one salt comprising a Group 4-13 metal, a lanthanide metal, or an actinide metal; and at least one organic counterion derived from an organic acid having a pKa relative to water of 0 or greater; and at least one organic sulfur compound; to form a first product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide; (B) separating the metal halide from the first product mixture; and (C) contacting at least a portion of the metal halide and an aromatic compound with chlorine or bromine, and at least one organic sulfur compound; to form a second product mixture comprising a monochloro or a monobromo aromatic compound and a Group 4-13 metal halide, a lanthanide metal halide or an actinide metal halide.ving a pKa relative to water of 0 or greater; and at least one organic sulfur compound.

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