Chemistry of inorganic compounds – Rare earth compound
Reexamination Certificate
2011-04-19
2011-04-19
Langel, Wayne (Department: 1736)
Chemistry of inorganic compounds
Rare earth compound
C423S387000
Reexamination Certificate
active
07927569
ABSTRACT:
Metallic clusters can be produced by contacting a metal salt such as a metal nitrate with an organic reducing agent. Metals can be selected from a group consisting of metals exhibiting octahedral coordination, and nitrates of the selected metal or metals are contacted with, for example nitrosobenzene. Binary, tertiary, or other clusters can be produced.
REFERENCES:
Jeremy C. Goodwin, et al.; “How Do Clusters Grow? The Synthesis and Structure of Polynuclear Hydroxide Gallium (III) Clusters”; Angew. Chem. Int. Ed. 2004, 43, 4037-4041; Copyright 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhiem (5 pages).
Wilhelm Seichter, et al.; “Crystal Structure and Formation of the Aluminum Hydroxide Chloride [Al13(OH)24(H20)24]Cl15 . 13 H2O”; Eur. J. Inorg. Chem. 1998 795-797; Copyright 1998 Wiley-VCH Verlag GmbH, D-69451, Weinhiem (3 pages).
Olga A. Gerasko, et al.; “Synthesis and Crystal Structure of Unprecedented Oxo/Hydroxo-Bridged Polynuclear Gallium(III) Aqua Complexes”; Inorganic Chemistry, vol. 44, No. 12, 2005 4133-4135; Copyright 2005 American Chemical Society (3 pages).
Sarah L. Heath, et al.; “Comparative X-ray and 27-AL NMR Spectroscopic Studies of the Speciation of Aluminum in Aqueous Systems: Al(III) Complexes of N(CH2CO2H)2(CH2CH20H)”; Journal of Inorganic Biochemistry 59, 785-794 (1995); Copyright 1995 Elsevier Science Inc.; New York (10 pages).
Elisabeth Rather, et al., “A Simple Organic Reaction Mediates the Crystallization of the Inorganic Nanocluster [Ga13(μ3-OH)6(μ2-OH)18(H2O)24](NO3)15”; J. Am. Chem. Soc., 2005, 127, 3242-3243; Copyright 2005 American Chemical Society (2 pages).
Wolfgang Schmitt et al; “[AL15(μ3-O)4(μ3-OH)6(μ-OH)14(hpdta)4]3×—A new Al15 Aggregate Which Forms a Supramolecular Zeotype”; Angew. Chem. Int Ed. 2001, 40, No. 19; Copyright 2001 Wiley-Vch Verlag GmbH, D-69451 Weinheim; 5 pages.
William H. Casey et al; A New Aluminum Hydroxide Octamer, [AL8(OH)14(H2O)18])SO4)5×16H2O Inorg. Chem. vol. 44, No. 14 (2005); Copyright 2005 American Chemical Society; 3 pages.
Gatlin Jason T.
Healey Elisabeth Rather
Johnson Darren W.
Mensinger Zachary L.
Klarquist & Sparkman, LLP
Langel Wayne
State of Oregon Acting By and Through the State Board of Higher
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