Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite
Patent
1996-10-10
1999-09-28
Bell, Mark L.
Chemistry of inorganic compounds
Zeolite
Organic compound used to form zeolite
423702, 423703, 423704, 423705, 423706, 423707, 423708, 423713, C01B 3700
Patent
active
059583673
ABSTRACT:
The present invention relates to a composition and a method for producing hexagonally-packed mesoporous metal oxides wherein the metal oxide is selected from transition metals and lanthanide metals. The composition includes hexagonally packed metal oxide mesostructures that are resistant to pore collapse upon removal of surfactant and are thermally stable. The composition can include a surfactant complexed with the metal. Also described are methods for producing the hexagonally-packed mesoporous metal oxides. The present invention also relates to compositions and methods for producing porous metal oxides. The compositions include microporous and mesoporous metal oxides that are resistant to pore collapse upon removal of surfactant and are thermally stable. Also described are methods for producing microporous metal oxides.
REFERENCES:
patent: 5098684 (1992-03-01), Kresge et al.
patent: 5102643 (1992-04-01), Kresge et al.
patent: 5211934 (1993-05-01), Kresge et al.
patent: 5250282 (1993-10-01), Kresge et al.
patent: 5264203 (1993-11-01), Beck et al.
patent: 5300277 (1994-04-01), Kresge et al.
patent: 5304363 (1994-04-01), Beck et al.
patent: 5308602 (1994-05-01), Calabro et al.
patent: 5362695 (1994-11-01), Beck et al.
A. Stein et al., "Salt-Gel Synthesis of Porous Transition Metal Oxides," Chem. Mater., 7(2) pp. 304-313 (1995). No Month|
D. M. Antonelli and J. Y. Ying, "Synthesis of Hexagonally Packed Mesoporous TiO.sub.2 by a Modified Sel-Gel Method," Angew. Chem. Int. Ed. Engl. 34(18):2014-2017 (1995) no month. provided.
D. M. Antonelli and J. Y.Ying. "Synthesis and Characterization of Hexagonally Packed Mesoporous Tantalum Oxide Molecular Sieves," Chem. Mater. 8:874-881 (1996) no month provided.
D. M. Antonelli and J. Y. Ying, "Synthesis of Stable Hexagonally Packed Mesoporous Niobium Oxide Molecular Sieve Through a Novel Ligand-Assisted Templating Mechanism," Angew. Chem. Int. Ed. Engl. 35(4):426-430 (1996) no month provided.
V. Luca, et al. "Synthesis and Characterization of Mesostructured Vanadium Oxide," Chem. Mater. 7:2220-2223 (1995) no month provided.
Q. Huo et al. "Generalized Synthesis of Periodic Surfactant/Inorganic Composite Materials," Nature, 368:317-321 (Mar. 1994).
Q. Huo, et al., "Organization of Organic Molecules with Inorganic Molecular Species in Nanocomposite Biphase Arrays," Chem. Mater. 6:1176-1191 (1994) no month provided.
T. Abe, et al. "Non-Silica-Based Mesostructured Material. 1. Synthesis of Vanadium Oxide-Based Materials," Chem. Mater. 7:1429-1430 (1995) no month provided.
N. K. Raman, et al., "Template-Based Approaches to the Preparation of Amorphous, Nanoporous Silicas," Chem. Mater. 8:1682-1701 (1996) no month provided.
6115 -- High-Tech Materials Alert, 10(11):2, (Nov. 1993), Englewood, NJ, US.
Monnier, A., et al., "Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures," Science, 261:1299-1303 (Sept. 3, 1990).
Chen, C., et al., "Studies on Mesoporous Materials . I. Synthesis and Characterization of MCM-41," Microporous Materials, 2:17-26 (1993).
Beck, J. S., et al., "Molecular or Supramolecular Templating: Defining the Role of Surfactant Chemistry in the Formation of Microporous and Mesoporous Molecular Sieves," Chem. Mater., 6:1816-1821 (1994).
Beck, J. S., et al., "A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates," J. Am. Chem. Soc., 114 (27):10834-10842 (1992).
Tanev, P. T., et al., "Titanium-Containing Mesoporous Molecular Sieves for Catalytic Oxidation of Aromatic Compounds," Nature, 368:321-323 (1994).
Huo, Q., et al., "Generalized Synthesis of Periodic Surfactant/Inorganic Composite Materials," Nature, 368:317-321 (1994).
Tanev, P. T. and Pinnavaia, T. J., "A neutral Templating Route to Mesoporous Molecular Sieves," Science, 267:865-867 (Feb. 10, 1995).
Huo, Q., et al., "Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays," Chem. Mater., 6:1176-1191 (1994). No month available.
Kresge, C. T., et al., "Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template Mechanism," Nature, 359:710-712 (Oct. 22, 1992).
Abe, T., et al., "Non-Silica-Based Mesostructed Materials. 1. Synthesis of Vanadium Oxide-Based Materials," Chem. Mater., 7:1429-1430 (1995). No month available.
Antonelli David M.
Sun Tao
Ying Jackie Y.
Bell Mark L.
Massachusetts Institute of Technology
Troilo Louis M.
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