Methods for preparing cycloalkylidene bisphenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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Reexamination Certificate

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07015365

ABSTRACT:
A process for forming a cycloalkylidene bisphenol comprises: reacting a cycloalkanone compound of formula:where [A] is a substituted or an unsubstituted aromatic group, R1–R4independently represent a hydrogen or a C1–C12hydrocarbyl group; and “a” and “b” are integers independently having values from 0–3; with an aromatic hydroxy compound of formula [A]-OH, where [A] is as previously described; at a mole ratio of greater than or equal to about 20, in the presence of a sulfonic acid type ion exchange resin catalyst crosslinked with greater than or equal to about 8 weight percent of divinylbenzene, and a promoter selected from the group consisting of a mercaptan compound and a resorcinol compound; to form a cycloalkylidene bisphenol of formula:where [A], R1–R4, “a” and “b” are as previously described. Moreover, any acid catalyst can be used with a resorcinol promoter.

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